{"id":"W2074327581","doi":"10.1039/c2dt30171g","title":"Chemistry of the heavy group 15 elements with the pyridyl tethered 1,2-bis(imino)acenaphthene “clamshell” ligand","year":2012,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; State Key Laboratory of Automotive Simulation and Control","keywords":"Acenaphthene; Chemistry; Ligand (biochemistry); Synthon; Pnictogen; Hypervalent molecule; Cycloaddition; Yield (engineering); Group (periodic table); Medicinal chemistry; Stereochemistry; Organic chemistry; Phenanthrene","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001790075,0.0002552981,0.0002452643,0.00002254926,0.0003792064,0.00004669579,0.0004992566,0.0001214483,0.007252026],"category_scores_gemma":[0.00001189446,0.0001517405,0.0001742789,0.0003047044,0.000193712,0.0001710629,0.00002101059,0.0002885919,0.00001321329],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006784418,"about_ca_system_score_gemma":0.00007050525,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003294175,"about_ca_topic_score_gemma":0.0000199876,"domain_scores_codex":[0.9985809,0.00002973443,0.0003871211,0.0002386394,0.0003958951,0.0003677039],"domain_scores_gemma":[0.9986865,0.0001167733,0.0002563735,0.000749913,0.00007593884,0.0001144844],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005830118,0.0005237583,0.002043641,0.00009909674,0.0002360835,3.32288e-7,0.0006940058,0.00001325797,0.9931853,0.00004279019,0.0001583665,0.002945041],"study_design_scores_gemma":[0.0006199902,0.00001646701,0.004936203,0.00006522654,0.0002019864,0.00004112986,0.001069147,0.00005518271,0.918505,0.000009978618,0.07422498,0.0002547675],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986973,0.0002440335,0.002764808,0.001348889,0.0001666818,0.0001489124,0.0001675898,0.00007259162,0.008113439],"genre_scores_gemma":[0.9939105,0.00005228903,0.00007753258,0.0001234119,0.0001822521,0.00004553357,0.00003253102,0.0000517596,0.005524178],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07468039,"threshold_uncertainty_score":0.9936555,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01374609881381094,"score_gpt":0.2112947627023521,"score_spread":0.1975486638885411,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}