{"id":"W2074327906","doi":"10.1021/jp075300i","title":"Role of the Aerosol Substrate in the Heterogeneous Ozonation Reactions of Surface-Bound PAHs","year":2007,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":148,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Ozone; Anthracene; Chemistry; Aerosol; Substrate (aquarium); Pyrene; Hydrocarbon; Adsorption; Reaction rate; Polycyclic aromatic hydrocarbon; Reaction rate constant; Kinetics; Analytical Chemistry (journal); Photochemistry; Physical chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002363743,0.0005500365,0.000415744,0.0001067221,0.0001964408,0.000662497,0.0003622478,0.0003202183,0.0009494477],"category_scores_gemma":[0.0004586341,0.0001958885,0.0003099594,0.00009560116,0.0002997692,0.0005601585,0.0004545799,0.0004577588,0.0003603394],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002440442,"about_ca_system_score_gemma":0.0002333549,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001117777,"about_ca_topic_score_gemma":0.001125179,"domain_scores_codex":[0.9996545,0.00005679932,0.00001880776,0.00009644086,0.0001114233,0.00006192148],"domain_scores_gemma":[0.9997681,0.0001077367,0.00003709234,0.0000146283,0.00005051567,0.00002195679],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001401723,0.00001605383,0.002162664,0.0001161968,0.00002260056,0.0001026799,0.00004296659,0.0003930097,0.994512,0.0001449705,0.00002801267,0.002318608],"study_design_scores_gemma":[0.00000981121,0.0001611809,0.006295502,0.000007110142,0.00002411782,0.00008741517,0.00008622506,0.002983966,0.9895828,0.00008111024,0.0006721035,0.000008715292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935062,0.001147703,0.003674776,0.00004964771,0.00002854793,0.00003229997,0.0001724172,0.00003785852,0.001350528],"genre_scores_gemma":[0.9975498,0.0004893157,0.001328253,0.00002222453,0.000005824393,0.00001324814,0.0001458202,0.00001369924,0.0004317753],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001117777,"threshold_uncertainty_score":0.003176212,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009981846957871899,"score_gpt":0.2199730363029442,"score_spread":0.2099911893450723,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}