{"id":"W2074561471","doi":"10.1021/ic035377v","title":"Lithiation of (<sup>t</sup>BuNH)<sub>3</sub>PNSiMe<sub>3</sub> and Formation of Tetraimidophosphate Complexes Containing M<sub>3</sub>O<sub>3</sub> Rings (M = Li, K):  X-ray Structure of the Stable Radical {(Me<sub>3</sub>SiN)P(μ<sub>3</sub>-N<sup>t</sup>Bu)<sub>3</sub>[μ<sub>3</sub>-Li(THF)]<sub>3</sub>(O<sup>t</sup>Bu)}","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; University of Lethbridge","funders":"","keywords":"Chemistry; Dilithium; Dimer; Alkali metal; Crystallography; Nuclear magnetic resonance spectroscopy; Lithium (medication); Solid-state; Hydride; Molecule; Formula unit; Stoichiometry; Stereochemistry; Medicinal chemistry; Metal; Crystal structure; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.005810754,0.01117513,0.01152109,0.00275643,0.004963801,0.002504925,0.009020591,0.009871161,0.0004424721],"category_scores_gemma":[0.006221182,0.01232702,0.005564227,0.01081467,0.006874847,0.00710946,0.005663615,0.01260043,0.0005679657],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.007553314,"about_ca_system_score_gemma":0.006272162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002296538,"about_ca_topic_score_gemma":0.0004248674,"domain_scores_codex":[0.950448,0.001872108,0.01570402,0.01081409,0.01073047,0.0104313],"domain_scores_gemma":[0.9609101,0.004269043,0.01277982,0.01030172,0.006331679,0.005407678],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003380422,0.003984565,0.003121945,0.01102714,0.00380086,0.0005006263,0.008520924,0.01959459,0.9254993,0.0002963381,0.003312397,0.01696084],"study_design_scores_gemma":[0.02048326,0.001048183,0.002572178,0.005362883,0.00433857,0.002228206,0.007169825,0.01215187,0.9305719,0.002602006,0.000766535,0.01070462],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9729705,0.005002793,0.002045759,0.001435814,0.001681098,0.00592196,0.007163664,0.002903042,0.0008753636],"genre_scores_gemma":[0.9746201,0.007255516,0.0005346581,0.00134551,0.004234472,0.001016283,0.008019877,0.002903944,0.00006964181],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01710284,"threshold_uncertainty_score":0.9993613,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007490018233458065,"score_gpt":0.199472607849342,"score_spread":0.1919825896158839,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}