{"id":"W2074800658","doi":"10.1134/s0020168507040085","title":"Effect of the chemical structure of silyl derivatives of unsymmetrical dimethylhydrazine on the composition and structure of silicon carbonitride films: Theoretical and experimental studies","year":2007,"lang":"en","type":"article","venue":"Inorganic Materials","topic":"Diamond and Carbon-based Materials Research","field":"Materials Science","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Ministère de l'Économie, de la Science et de l'Innovation - Québec","keywords":"Homolysis; Dimethylhydrazine; Chemistry; Silanes; Decomposition; Silicon; Silane; Silylation; Thermal decomposition; Endothermic process; Dimethylsilane; Physical chemistry; Inorganic chemistry; Organic chemistry; Adsorption; Radical; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008902832,0.0002170858,0.0007079302,0.00008433024,0.00005323756,0.0000226359,0.0002833583,0.0001310534,0.0003774774],"category_scores_gemma":[0.0006721402,0.0001105603,0.00004845805,0.0002227223,0.001710173,0.00004521862,0.0002942017,0.00008732548,2.380937e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000221403,"about_ca_system_score_gemma":0.00003036218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004384021,"about_ca_topic_score_gemma":9.915194e-7,"domain_scores_codex":[0.9978715,0.0005816033,0.0006160128,0.0002480715,0.0004576605,0.0002251624],"domain_scores_gemma":[0.9975125,0.001660518,0.00035513,0.0003059987,0.0001157382,0.00005018352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000899702,0.00005310163,0.000297575,0.0004525649,0.00004273472,8.47685e-7,0.0005194186,0.000001563511,0.9924184,0.00526016,0.000007259211,0.00004667763],"study_design_scores_gemma":[0.0006301548,0.0005819841,0.001460474,0.0001503079,0.00004865195,0.000006650827,0.0002787599,0.000002868178,0.9958807,0.0008649706,3.64919e-7,0.0000941472],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983021,0.0006300816,0.000001450618,0.00004606001,0.0002078023,0.000447058,0.0003340198,0.000008086929,0.00002335735],"genre_scores_gemma":[0.9998335,0.00002106174,0.0000514608,0.0000224671,0.00004584291,0.000003007341,0.000005612539,0.00001624217,8.031162e-7],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00439519,"threshold_uncertainty_score":0.6301203,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006736828940993781,"score_gpt":0.281685534694771,"score_spread":0.2749487057537773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}