{"id":"W2075039424","doi":"10.1002/chin.200941254","title":"ChemInform Abstract: Preparation of Chiral Diamines by the Diaza‐Cope Rearrangement (DCR)","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004309576,0.0006969071,0.0004253579,0.0006688786,0.0004137896,0.0002491458,0.0009839999,0.0004313679,0.01989902],"category_scores_gemma":[0.0004429148,0.0002698671,0.0002999979,0.0005358324,0.0003254389,0.0005456541,0.000436324,0.001378527,0.007347526],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00062298,"about_ca_system_score_gemma":0.0008731413,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001038193,"about_ca_topic_score_gemma":0.001528071,"domain_scores_codex":[0.9997194,0.00002832213,0.00001388941,0.00006943633,0.00009030574,0.00007853819],"domain_scores_gemma":[0.9998863,0.00002249631,0.00002052074,0.00001636178,0.00002097031,0.00003333947],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008173158,0.0001525715,0.0002230298,0.001497963,0.00006510896,0.0009303624,0.0002032337,0.001301197,0.914809,0.008121292,0.02811139,0.04376751],"study_design_scores_gemma":[0.0001726319,0.0006265274,0.0005597518,0.00004299082,0.00002859208,0.0006869367,0.00003077365,0.001097553,0.9527559,0.0007891108,0.04315996,0.00004923825],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4728259,0.01096553,0.2045833,0.004446984,0.004108477,0.001940819,0.0135902,0.005534804,0.2820041],"genre_scores_gemma":[0.8922827,0.008562028,0.0339023,0.00124416,0.0004032203,0.0004376569,0.005469822,0.0008763841,0.05682166],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01989902,"threshold_uncertainty_score":0.06656885,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05775269491469429,"score_gpt":0.4041730376654598,"score_spread":0.3464203427507655,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}