{"id":"W2075154254","doi":"10.1021/om300410h","title":"Diamido-Ether Actinide Complexes as Catalysts for the Intramolecular Hydroamination of Aminoalkenes","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; Simon Fraser University","funders":"","keywords":"Hydroamination; Chemistry; Intramolecular force; Medicinal chemistry; Diethyl ether; Ether; Catalysis; Alkylation; Alkyl; Reactivity (psychology); Actinide; Halide; Thorium; Organic chemistry; Uranium; Nuclear chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002158586,0.0001662341,0.0002153341,0.00005797514,0.0001329646,0.00002538704,0.0002792043,0.0001005469,0.0004763128],"category_scores_gemma":[0.0003998708,0.000131609,0.0001531616,0.0002214358,0.0001513348,0.0001820185,0.00007362116,0.0001189241,0.00007394882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000085875,"about_ca_system_score_gemma":0.00004817508,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001273836,"about_ca_topic_score_gemma":0.00002301856,"domain_scores_codex":[0.9990209,0.00001066069,0.0002780634,0.0001678282,0.000232416,0.0002901227],"domain_scores_gemma":[0.9985554,0.0005277146,0.0002091364,0.0005287474,0.00009875722,0.00008028487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001979325,0.0003081224,0.001494008,0.0001547195,0.0003592823,5.820865e-7,0.0009600658,0.00000937206,0.9707894,0.009414598,0.0003733684,0.01611672],"study_design_scores_gemma":[0.0002921463,0.00001308533,0.002660386,0.00001290256,0.0002999909,0.00003002356,0.0007022548,0.0001249624,0.9398952,0.0004388212,0.0553402,0.0001900043],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830548,0.0009706395,0.002832193,0.0004590579,0.0002145899,0.0002539546,0.00007928524,0.00007704994,0.0120585],"genre_scores_gemma":[0.9964169,0.00004893816,0.0004629713,0.0000384659,0.0002532658,0.00005959892,0.0001732444,0.00005035121,0.00249628],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05496683,"threshold_uncertainty_score":0.5366859,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01915528357322625,"score_gpt":0.2721765864365569,"score_spread":0.2530213028633306,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}