{"id":"W2075208571","doi":"10.1021/ic001446j","title":"Preparation, Characterization, and Luminescence Properties of Gallium−Metal Face-to-Face Diporphyrins (M = H<sub>2</sub>, GaL, Ru(CO)(OH), Co)","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Intramolecular force; Luminescence; Fluorescence; Phosphorescence; Crystallography; Ligand (biochemistry); Metal; Anthracene; Photochemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00011511,0.0002313571,0.0001388131,0.0001215221,0.0001115784,0.0002343891,0.0001822856,0.0002078333,0.0004717584],"category_scores_gemma":[0.0002713744,0.0001197019,0.0000900522,0.0001151837,0.0001768864,0.0002211721,0.0002292871,0.000367153,0.0002389603],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001777111,"about_ca_system_score_gemma":0.000123665,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003025269,"about_ca_topic_score_gemma":0.0003833038,"domain_scores_codex":[0.9998968,0.00001132126,0.000006998223,0.00002822092,0.00004197213,0.00001466804],"domain_scores_gemma":[0.9998232,0.0000314903,0.00004989034,0.00002928977,0.00002854908,0.0000375954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009255837,0.000005186743,0.00008941771,0.00001448208,0.00000128492,0.00001110686,0.000004923511,0.00002634131,0.9986243,0.00001095235,0.000008913958,0.001193807],"study_design_scores_gemma":[0.000004194712,0.0001330593,0.003076472,0.00000192825,0.000007270244,0.0002040617,0.000008885967,0.0002765752,0.995235,0.00001225643,0.00103687,0.0000034913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941778,0.0005839898,0.004264726,0.00005142725,0.000007804458,0.00004842999,0.0001602539,0.0000513824,0.0006540449],"genre_scores_gemma":[0.987376,0.000460616,0.01029847,0.00003946372,0.000008984223,0.00006092347,0.0003626031,0.00002934225,0.001363738],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004717584,"threshold_uncertainty_score":0.001578212,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01379832634586155,"score_gpt":0.2369275316826338,"score_spread":0.2231292053367723,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}