{"id":"W2075464084","doi":"10.1039/b516814g","title":"Electrochemical oxidation of catechol in the presence of cyclopentadiene. Investigation of electrochemically induced Diels–Alder reactions","year":2006,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Cyclopentadiene; Cycloaddition; Catechol; Electrochemistry; Benzoquinone; Chemistry; Diels–Alder reaction; Photochemistry; Redox; Kinetic energy; Organic chemistry; Electrode; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002888462,0.0002913395,0.0002150806,0.0001211134,0.0001402709,0.0003686996,0.0003224657,0.0003198317,0.001092389],"category_scores_gemma":[0.0005420535,0.0001749154,0.0001682528,0.0001935189,0.0002004501,0.0003889746,0.0001527916,0.0005496133,0.0002495578],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003755234,"about_ca_system_score_gemma":0.000182348,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008656291,"about_ca_topic_score_gemma":0.001614407,"domain_scores_codex":[0.9996985,0.0000356134,0.0000163442,0.00005802409,0.0001238702,0.00006776745],"domain_scores_gemma":[0.9997385,0.00009564421,0.00005689594,0.00003082729,0.00005564148,0.00002255795],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004275779,0.00002336837,0.0001747313,0.0000670516,0.000009344866,0.00004628694,0.00003856535,0.00008013471,0.9977342,0.0001228512,0.00003555455,0.001625222],"study_design_scores_gemma":[0.000003736045,0.00006723974,0.0007884573,0.00000233992,0.000005749282,0.00005771319,0.00001827822,0.0003465358,0.9979644,0.0000252931,0.0007171794,0.000003154959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9880245,0.001586546,0.007196059,0.0001380358,0.00005760688,0.00003334644,0.0003483814,0.00006374457,0.0025517],"genre_scores_gemma":[0.994197,0.001026849,0.002589822,0.00003243196,0.00001219032,0.00001820496,0.0002844199,0.00001248921,0.001826439],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001092389,"threshold_uncertainty_score":0.003654361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02383772250547302,"score_gpt":0.2653579663421731,"score_spread":0.2415202438367001,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}