{"id":"W2075526139","doi":"10.1039/b407801b","title":"Evidence of homolytic and heterolytic pathways in the photodissociation of iminosulfonates and direct detection of the p-toluenesulfonyloxyl radical","year":2004,"lang":"en","type":"article","venue":"Photochemical & Photobiological Sciences","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":false,"ca_institutions":"Cégep Saint-Jean-sur-Richelieu; University of Ottawa","funders":"","keywords":"Heterolysis; Homolysis; Photochemistry; Chemistry; Flash photolysis; Photodissociation; Dissociation (chemistry); Radical; Hydroxyl radical; Radical ion; Reaction rate constant; Ion; Kinetics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0008075006,0.0002061844,0.0004429126,0.00004963598,0.0001267802,0.0000209711,0.0006506959,0.0002439075,0.00003800976],"category_scores_gemma":[0.003200165,0.0001103894,0.0001534104,0.0006459204,0.003396726,0.0001171799,0.000178926,0.0003729125,3.882975e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008247488,"about_ca_system_score_gemma":0.00007817378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006040688,"about_ca_topic_score_gemma":0.00003476168,"domain_scores_codex":[0.9979106,0.00009813631,0.0006714958,0.0004750534,0.0005248115,0.0003199618],"domain_scores_gemma":[0.9971263,0.002057141,0.0003876775,0.0002797268,0.00006023718,0.00008885691],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007896188,0.0002031868,0.005223325,0.00009260697,0.00000940581,7.997762e-7,0.0002538887,0.00001248447,0.9936173,0.0001316057,0.000001483548,0.0003749811],"study_design_scores_gemma":[0.0004353951,0.0001793676,0.01161882,0.0003637141,0.00003219995,0.0000238818,0.0002092034,0.0002313408,0.9799818,0.006787558,0.000009025083,0.0001276559],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977239,0.0009088868,0.000006273791,0.0001704347,0.00002575069,0.0004137216,0.00002288364,0.0000163675,0.0007118104],"genre_scores_gemma":[0.9994745,0.0002404919,0.00008269894,0.00007291829,0.00001786283,0.0001024667,0.000001606854,0.000005377268,0.000002131407],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01363543,"threshold_uncertainty_score":0.9993154,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04067141832235709,"score_gpt":0.2683511517035285,"score_spread":0.2276797333811714,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}