{"id":"W2075893154","doi":"10.1016/j.ces.2005.12.015","title":"Oxidation kinetics of Iron(II) complexes of trans-1,2-diaminocyclohexanetetraacetate (cdta) with dissolved oxygen: Reaction mechanism, parameters of activation and kinetic salt effects","year":2006,"lang":"en","type":"article","venue":"Chemical Engineering Science","topic":"Metal Extraction and Bioleaching","field":"Engineering","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Oxidizing agent; Oxygen; Redox; Reaction rate constant; Kinetics; Inorganic chemistry; Reaction mechanism; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002324877,0.0002027593,0.000257336,0.00009797226,0.00009809276,0.0002089445,0.0002756623,0.0003701845,0.0008286427],"category_scores_gemma":[0.0005449716,0.0001385718,0.0001513964,0.0001340754,0.0001750917,0.0002133551,0.0001125526,0.0002631011,0.0001480115],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003706703,"about_ca_system_score_gemma":0.0001319321,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001484694,"about_ca_topic_score_gemma":0.001410972,"domain_scores_codex":[0.9998407,0.00002530226,0.00001314122,0.00003709121,0.00004161823,0.00004213886],"domain_scores_gemma":[0.9998044,0.00008514694,0.00004143565,0.00001363692,0.00003548759,0.00001979727],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008148263,0.00002403752,0.0006826137,0.00006299757,0.000009457013,0.00003768536,0.00006972816,0.000281252,0.995775,0.0001017243,0.00004787239,0.002092763],"study_design_scores_gemma":[0.00001747845,0.0002016567,0.001694652,0.000002632425,0.00001095283,0.00004713435,0.00001792824,0.003039472,0.9944828,0.00002347295,0.0004579672,0.000004009022],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998347,0.0003147257,0.0008994029,0.00002367124,0.000006751568,0.000005449273,0.00005552315,0.00001845925,0.0003289924],"genre_scores_gemma":[0.998601,0.0001347793,0.0004930262,0.00000825313,0.000002374853,0.00000385254,0.00009482067,0.000006672336,0.0006552348],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001484694,"threshold_uncertainty_score":0.002952099,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006091023154205659,"score_gpt":0.1890582779637242,"score_spread":0.1829672548095186,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}