{"id":"W2076226719","doi":"10.1021/om010274a","title":"Decomplexation of Cyclopentadienylmanganese Tricarbonyls under Very Mild Conditions:  A Novel Route to Substituted Cyclopentadienes and Their Application in Organometallic Synthesis","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Cyclopentadienyl complex; Rhenium; Cyclopentadiene; Intramolecular force; Ligand (biochemistry); Yield (engineering); Photochemistry; Molecule; Methanol; Photodissociation; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003897094,0.0005199643,0.0009530043,0.0007959061,0.0001679289,0.00009571552,0.0006198641,0.0001908881,0.004299027],"category_scores_gemma":[0.0002898726,0.0004902532,0.0002079135,0.002512251,0.0001962286,0.0004020766,0.0002611451,0.0001829262,0.00005485952],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002816947,"about_ca_system_score_gemma":0.00008378176,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005537957,"about_ca_topic_score_gemma":0.001111711,"domain_scores_codex":[0.9971878,0.00005143368,0.001003723,0.0008756379,0.0003416232,0.0005398061],"domain_scores_gemma":[0.9977539,0.0005163277,0.0003960844,0.0009073983,0.0001413854,0.0002849374],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0001374445,0.001313783,0.02965243,0.0001830927,0.0004840849,0.000007114451,0.0008216416,0.0003834653,0.9328053,0.004495346,0.000007937783,0.02970835],"study_design_scores_gemma":[0.004188844,0.0001188118,0.6560016,0.0004431696,0.001077021,0.0002457201,0.00917587,0.003469708,0.2785206,0.002920339,0.04049507,0.003343301],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918408,0.0005463925,0.003069533,0.0003781696,0.000046519,0.0004287798,0.0002146844,0.00009831959,0.003376821],"genre_scores_gemma":[0.9972412,0.0005526507,0.0007924316,0.0001100361,0.00007311687,0.0002793976,0.0002782176,0.00008968802,0.0005832844],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6542848,"threshold_uncertainty_score":0.9997549,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.021113126206777,"score_gpt":0.2449044570061001,"score_spread":0.2237913307993231,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}