{"id":"W2076266734","doi":"10.1063/1.3259877","title":"Translational and internal energy distributions of methyl and hydroxyl radicals produced by 157nm photodissociation of amorphous solid methanol","year":2009,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Photoexcitation; Methanol; Radical; Photodissociation; Chemistry; Photochemistry; Kinetic energy; Internal energy; Resonance-enhanced multiphoton ionization; Hydroxyl radical; Analytical Chemistry (journal); Ionization; Excited state; Photoionization; Atomic physics; Ion; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001458142,0.0001367265,0.0003979133,0.00001410972,0.00004061409,0.000005979793,0.000142047,0.00003105715,0.000004867781],"category_scores_gemma":[0.00002676844,0.0001003822,0.0001162147,0.0001102629,0.0002391336,0.000132418,0.00002647484,0.0002105838,7.072488e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000174392,"about_ca_system_score_gemma":0.00002447918,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001184004,"about_ca_topic_score_gemma":3.278212e-8,"domain_scores_codex":[0.9990101,0.00004376511,0.0004542873,0.00009677003,0.0002584038,0.0001366681],"domain_scores_gemma":[0.9988419,0.0002317318,0.0005934897,0.00009771594,0.0001691683,0.00006597258],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000659802,0.0002111596,0.00009717087,0.000008423922,0.0001781023,7.769721e-8,0.0002502543,0.00004302387,0.9859633,0.004398267,0.0002563389,0.008527936],"study_design_scores_gemma":[0.0004190906,0.00005190784,0.00008072588,0.00002853231,0.0001171368,0.000001089498,0.00002686634,0.0001084747,0.7417835,0.2572897,0.00002484001,0.00006807888],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9567825,0.0005971233,0.04164905,0.000477216,0.00002196092,0.00006415942,0.0001190327,0.000003967813,0.0002850353],"genre_scores_gemma":[0.9992994,0.0000442878,0.0003891369,0.00001921459,0.0002194087,0.000001180441,0.00001399461,0.00000704169,0.000006338103],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2528915,"threshold_uncertainty_score":0.4093466,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006002154988312074,"score_gpt":0.2510002441166042,"score_spread":0.2449980891282921,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}