{"id":"W2076282016","doi":"10.1016/j.carres.2013.05.001","title":"Role of the 4,6-O-acetal in the regio- and stereoselective conversion of 2,3-di-O-sulfonyl-β-d-galactopyranosides to d-idopyranosides","year":2013,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"Alberta Glycomics Centre; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Alberta","keywords":"Chemistry; Stereoselectivity; Sulfonyl; Acetal; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003202198,0.0003317802,0.0001112855,0.0001712474,0.0001624025,0.0002850528,0.0002551957,0.0002122606,0.001236303],"category_scores_gemma":[0.0002353709,0.0001126253,0.0001186336,0.0001505067,0.0003521239,0.0003618666,0.0002668984,0.0003736433,0.0004705047],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001407495,"about_ca_system_score_gemma":0.0003181976,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007853074,"about_ca_topic_score_gemma":0.001196207,"domain_scores_codex":[0.9998933,0.00002789693,0.000007054392,0.000009438072,0.00001765736,0.0000446656],"domain_scores_gemma":[0.9999045,0.00002262258,0.00001626427,0.00001595469,0.00001474184,0.00002587594],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001346656,0.0001245178,0.0008841944,0.00007825654,0.000009912455,0.0005502912,0.0001992738,0.0008948934,0.9788387,0.002711315,0.0001394677,0.0142224],"study_design_scores_gemma":[0.00003368022,0.0004486541,0.001081553,0.000007529923,0.00001135712,0.0001574169,0.00007995631,0.0008288044,0.9944322,0.0002615323,0.002644884,0.00001248746],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885994,0.0006902368,0.002980339,0.000161757,0.00006615352,0.00002051108,0.00008217862,0.00004292426,0.007356443],"genre_scores_gemma":[0.9970015,0.0004451241,0.0009632689,0.00003312356,0.00001208593,0.000005009192,0.00005180224,0.00001106595,0.001476996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001236303,"threshold_uncertainty_score":0.004135787,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0266199328431807,"score_gpt":0.2766919104131407,"score_spread":0.25007197756996,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}