{"id":"W2076282016","doi":"10.1016/j.carres.2013.05.001","title":"Role of the 4,6-O-acetal in the regio- and stereoselective conversion of 2,3-di-O-sulfonyl-β-d-galactopyranosides to d-idopyranosides","year":2013,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":false,"ca_institutions":"Alberta Glycomics Centre; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Alberta","keywords":"Chemistry; Stereoselectivity; Sulfonyl; Acetal; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000836105,0.0002119858,0.0003687126,0.0001586034,0.0001624014,0.00007178265,0.0008032356,0.0001903975,0.0002406295],"category_scores_gemma":[0.0005797469,0.0001357799,0.0001329012,0.0009803586,0.000684311,0.0001533459,0.0003348043,0.000560773,0.00001174794],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009306873,"about_ca_system_score_gemma":0.0001373698,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001315458,"about_ca_topic_score_gemma":0.00005270268,"domain_scores_codex":[0.9976016,0.0002976794,0.0004255647,0.0004048984,0.000753517,0.0005167296],"domain_scores_gemma":[0.9974993,0.001060849,0.0001217982,0.0007993538,0.0003976714,0.0001210572],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007829926,0.00008959904,0.01112046,0.0002517333,0.00003486019,0.000002897365,0.003329328,0.000007245609,0.9839557,0.0001168214,0.0002281459,0.000784932],"study_design_scores_gemma":[0.0003047531,0.0000414961,0.007527829,0.000206391,0.00001604566,0.000006445888,0.008009433,0.0003550856,0.9823807,0.0007955137,0.0002131082,0.0001431677],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9881203,0.0004038521,5.039897e-7,0.00080103,0.00002245805,0.0004103874,0.00002321694,0.00001191909,0.01020637],"genre_scores_gemma":[0.9992889,0.00009589328,0.00001276092,0.00002947588,0.00005911765,0.000145346,0.000003785592,0.00002379922,0.0003409229],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01116864,"threshold_uncertainty_score":0.5536945,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0266199328431807,"score_gpt":0.2766919104131407,"score_spread":0.25007197756996,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}