{"id":"W2076401558","doi":"10.1002/cphc.200900416","title":"Electron Transport and Redox Reactions in Molecular Electronic Junctions","year":2009,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Institute for Nanotechnology","funders":"","keywords":"Redox; Quantum tunnelling; Polaron; Electron transport chain; Chemical physics; Molecular electronics; Molecule; Electron transfer; Chemistry; Electron; Monolayer; Molecular switch; Charge (physics); Nanotechnology; Materials science; Photochemistry; Optoelectronics; Physics; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003018081,0.0002467922,0.0002422051,0.0004343128,0.000664937,0.001097669,0.0006162361,0.0009751558,0.001404963],"category_scores_gemma":[0.0004292213,0.0002271356,0.0001830474,0.0003445933,0.0007861572,0.002101468,0.0004469919,0.0006130417,0.000323426],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004457851,"about_ca_system_score_gemma":0.0001083819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003232762,"about_ca_topic_score_gemma":0.0002128539,"domain_scores_codex":[0.9999044,0.00001914121,0.00000481905,0.00002163699,0.00003228831,0.00001768995],"domain_scores_gemma":[0.9999204,0.00004334093,0.00001116727,0.000006546111,0.000009697249,0.000008861662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0004277185,0.0002603845,0.0007411356,0.0005115945,0.0000319799,0.001367587,0.0004822399,0.01707148,0.3093955,0.6334934,0.001413229,0.03480374],"study_design_scores_gemma":[0.0001289132,0.0006810798,0.002017941,0.000148142,0.00005809914,0.001653685,0.0004712221,0.0915949,0.3797944,0.4807465,0.04258145,0.0001236916],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8228878,0.07300494,0.04650352,0.00281251,0.0006987261,0.00006089389,0.0001375221,0.0001760036,0.05371805],"genre_scores_gemma":[0.9655386,0.01881472,0.004097575,0.0001728002,0.0002133248,0.00003427108,0.00007772627,0.00002433356,0.01102672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001404963,"threshold_uncertainty_score":0.004700124,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002643434064413682,"score_gpt":0.1888623945167715,"score_spread":0.1862189604523578,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}