{"id":"W2076464687","doi":"10.1002/(sici)1522-2683(20000101)21:1<198::aid-elps198>3.0.co;2-v","title":"Rapid and sensitive separation of trace level protein digests using microfabricated devices coupled to a quadrupole - time-of-flight mass spectrometer","year":2000,"lang":"en","type":"article","venue":"Electrophoresis","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":106,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Institute for Biological Sciences","funders":"","keywords":"Chromatography; Mass spectrometry; Chemistry; Sample preparation; Stacking; Analytical Chemistry (journal); Detection limit; Tandem mass spectrometry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005134524,0.001049928,0.0006794413,0.0006279264,0.0003596127,0.0008155975,0.001245538,0.001110519,0.000514066],"category_scores_gemma":[0.0005479669,0.0004769604,0.0003866608,0.0003574384,0.0004265782,0.0005292683,0.0005319194,0.0007375006,0.0006648429],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005706898,"about_ca_system_score_gemma":0.0005310251,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007160406,"about_ca_topic_score_gemma":0.001426248,"domain_scores_codex":[0.9992549,0.00006246333,0.00003393411,0.0002059953,0.000378854,0.00006388366],"domain_scores_gemma":[0.9997168,0.00009613896,0.00007087971,0.00003014597,0.00005831717,0.0000277211],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001316763,0.00001247978,0.00007129932,0.00004183009,0.000005663296,0.00002447826,0.000007569342,0.00004800726,0.9950421,0.00004969,0.00008490865,0.00459877],"study_design_scores_gemma":[0.000008682279,0.0001282351,0.002003146,0.000006278165,0.00001756811,0.0006159936,0.00001102482,0.002899725,0.9895077,0.0001277769,0.004650005,0.00002380578],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.3334025,0.009576962,0.6453856,0.000516989,0.0002611466,0.0004432658,0.001591922,0.005899352,0.002922216],"genre_scores_gemma":[0.3742273,0.005220366,0.6122202,0.0006223895,0.0001358597,0.0006507569,0.002157544,0.0002012495,0.004564351],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.001245538,"threshold_uncertainty_score":0.004140615,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01045560025769218,"score_gpt":0.2233133537628733,"score_spread":0.2128577535051811,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}