{"id":"W2076956133","doi":"10.1039/c3ob40115d","title":"Asymmetric synthesis of carbocycles: use of intramolecular conjugate displacement","year":2013,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Geminal; Intramolecular force; Chemistry; Conjugate; Deprotonation; Ring (chemistry); Adduct; Stereochemistry; Medicinal chemistry; Reduction (mathematics); Organic chemistry; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003740036,0.0005367579,0.0003130205,0.0002962225,0.0002134811,0.0003777852,0.0005154101,0.0003143028,0.001637218],"category_scores_gemma":[0.0004149569,0.0001929081,0.0003179483,0.0003217379,0.0003657462,0.0004431612,0.0005523596,0.0009311275,0.0006339838],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003624352,"about_ca_system_score_gemma":0.0004994432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004510416,"about_ca_topic_score_gemma":0.0007570079,"domain_scores_codex":[0.9997404,0.00003600764,0.00002538364,0.00006961171,0.00005662026,0.00007200906],"domain_scores_gemma":[0.9998029,0.00003459591,0.00003609743,0.00005546636,0.00003427078,0.00003666459],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001773178,0.0001649886,0.0003748577,0.0002295467,0.00004123237,0.000463699,0.0002427457,0.001074254,0.9516819,0.009880587,0.0005474331,0.03512144],"study_design_scores_gemma":[0.00003403223,0.0002772177,0.0002861755,0.00000430592,0.00001286027,0.0002159937,0.00001723098,0.0006481298,0.9927742,0.0002027907,0.00551509,0.000011798],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8454041,0.003464046,0.1145304,0.0005116097,0.0004469605,0.0007836262,0.0007216195,0.0006369494,0.03350073],"genre_scores_gemma":[0.9702172,0.001431085,0.02358684,0.00007405672,0.0000334226,0.000107594,0.0002067234,0.00005186916,0.00429133],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001637218,"threshold_uncertainty_score":0.005477071,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006745266132062972,"score_gpt":0.1923792536463568,"score_spread":0.1856339875142938,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}