{"id":"W2076973248","doi":"10.1074/jbc.m513893200","title":"A Weak Fe–O Bond in the Oxygenated Complex of the Nitric-oxide Synthase of Staphylococcus aureus","year":2006,"lang":"en","type":"article","venue":"Journal of Biological Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Raman spectroscopy; Oxygen; Ferric; Substrate (aquarium); Resonance Raman spectroscopy; Resonance (particle physics); Analytical Chemistry (journal); Crystallography; Inorganic chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008592644,0.0002239622,0.0005235576,0.00004801436,0.00005498624,0.00001748628,0.001125296,0.0002983717,0.0006809985],"category_scores_gemma":[0.0007416811,0.000114143,0.0003947717,0.0004399447,0.0002374203,0.00004506499,0.0001264855,0.0006123583,0.000001889515],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007430299,"about_ca_system_score_gemma":0.00009910411,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003376702,"about_ca_topic_score_gemma":0.000002619644,"domain_scores_codex":[0.9976391,0.00009196707,0.001234725,0.0001943669,0.0005756916,0.000264172],"domain_scores_gemma":[0.9973592,0.0003944256,0.001441747,0.0004611809,0.000276167,0.0000672401],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001102543,0.0003916123,0.001932585,0.0001010444,0.00004358599,0.00003192546,0.00002073526,0.00005971526,0.9962516,0.0001357196,0.0008480779,0.00007315604],"study_design_scores_gemma":[0.0008747905,0.0000240982,0.009828658,0.00007589759,0.00003801744,0.0001035183,0.0005022996,0.00005543598,0.9856213,0.001934761,0.0008086176,0.0001326171],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938911,0.0004351057,0.0000578089,0.0002695824,0.00002659453,0.00007869357,0.0001037182,0.000009078532,0.005128363],"genre_scores_gemma":[0.9990837,0.00002657579,0.0005241046,0.00005632272,0.0001329077,0.00000489217,0.00002439781,0.00001087095,0.0001362481],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0106303,"threshold_uncertainty_score":0.7456456,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03114545378822736,"score_gpt":0.2533782244349681,"score_spread":0.2222327706467407,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}