{"id":"W2077139480","doi":"10.1021/jo026917t","title":"Abnormal Solvent Effects on Hydrogen Atom Abstractions. 1. The Reactions of Phenols with 2,2-Diphenyl-1-picrylhydrazyl (dpph<sup>•</sup>) in Alcohols","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":414,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"Fundacja na rzecz Nauki Polskiej","keywords":"Chemistry; DPPH; Phenols; Hydrogen atom abstraction; Hydrogen atom; Solvent; Alcohol; Organic chemistry; Medicinal chemistry; Antioxidant; Photochemistry; Hydrogen; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004101834,0.0004111079,0.0001860776,0.0001547387,0.0001675715,0.0001897683,0.0001906473,0.0002084684,0.00111142],"category_scores_gemma":[0.00107586,0.0001369873,0.0001550427,0.0001334381,0.0002842005,0.0004950567,0.0002693908,0.0003289773,0.000305108],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001969655,"about_ca_system_score_gemma":0.0001442463,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006063314,"about_ca_topic_score_gemma":0.0005604124,"domain_scores_codex":[0.9997432,0.00009186238,0.00001769758,0.00003986218,0.00005663629,0.0000509023],"domain_scores_gemma":[0.9992499,0.0003588462,0.0001789361,0.00004055007,0.0001042595,0.00006751809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008998266,0.00001466432,0.001913064,0.0002354071,0.0000236968,0.0001467983,0.00009900377,0.0004427487,0.9917049,0.0002083343,0.00006886457,0.004242735],"study_design_scores_gemma":[0.000007176131,0.0002355697,0.002478658,0.000004444642,0.00001389015,0.0001280708,0.00002912302,0.0005784826,0.995909,0.00006584049,0.0005441884,0.000005616347],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925056,0.00411458,0.002073836,0.00006215207,0.00002470793,0.00001383549,0.0002170651,0.0000675488,0.0009206418],"genre_scores_gemma":[0.9977435,0.001001918,0.000631491,0.00001459375,0.000006891168,0.000006595878,0.0001844092,0.000009914475,0.0004007312],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00111142,"threshold_uncertainty_score":0.003718078,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007725297067702088,"score_gpt":0.2156561677878386,"score_spread":0.2079308707201365,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}