{"id":"W2077139480","doi":"10.1021/jo026917t","title":"Abnormal Solvent Effects on Hydrogen Atom Abstractions. 1. The Reactions of Phenols with 2,2-Diphenyl-1-picrylhydrazyl (dpph<sup>•</sup>) in Alcohols","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":414,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"Fundacja na rzecz Nauki Polskiej","keywords":"Chemistry; DPPH; Phenols; Hydrogen atom abstraction; Hydrogen atom; Solvent; Alcohol; Organic chemistry; Medicinal chemistry; Antioxidant; Photochemistry; Hydrogen; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007049566,0.0002721803,0.0003977119,0.00003618941,0.000177974,0.00003071809,0.0005598915,0.0001688893,0.001705475],"category_scores_gemma":[0.0001808909,0.0001574164,0.0001793701,0.0002638146,0.0001932335,0.0001242003,0.00003673103,0.001052481,0.0000190962],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001678484,"about_ca_system_score_gemma":0.0002631466,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001861519,"about_ca_topic_score_gemma":0.000006223238,"domain_scores_codex":[0.9980662,0.00006816321,0.0007586266,0.0001749547,0.0005724113,0.0003596404],"domain_scores_gemma":[0.9978769,0.0005363252,0.0007537214,0.0005834678,0.0001092112,0.0001403239],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001501309,0.0003880537,0.001157311,0.0002097203,0.0002307467,0.00006704582,0.0003182139,0.001215428,0.9955654,0.00003234702,0.0003122506,0.0003533951],"study_design_scores_gemma":[0.001455717,0.00006325571,0.0006068571,0.0005031715,0.000166359,0.001476267,0.0007810501,0.00005095304,0.9911919,0.0001963533,0.003322592,0.0001854738],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991445,0.0005875597,0.00004963523,0.000470238,0.0000415957,0.00008464596,0.00000831644,0.00001661726,0.007296359],"genre_scores_gemma":[0.9987279,0.0002824992,0.00007949463,0.00006162023,0.0002655729,0.000004340134,0.00000216456,0.00004305055,0.0005334265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007282799,"threshold_uncertainty_score":0.9992071,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007725297067702088,"score_gpt":0.2156561677878386,"score_spread":0.2079308707201365,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}