{"id":"W2077159230","doi":"10.1016/j.tetasy.2005.07.016","title":"2-Chlorobicyclo[2.2.1]hept-5-ene-2-carboxamide and 2-chlorobicyclo[2.2.1]heptane-2-carboxamide as precursors of bicyclo[2.2.1]hept-5-en-2-one and bicyclo[2.2.1]heptan-2-one: resolution, absolute configuration and hydrogen-bonding properties","year":2005,"lang":"en","type":"article","venue":"Tetrahedron Asymmetry","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of British Columbia; BioFine International (Canada); Simon Fraser University","funders":"","keywords":"Bicyclic molecule; Dimer; Chemistry; Carboxamide; Stereochemistry; Absolute configuration; Crystal structure; Moiety; Enantiomer; Ene reaction; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001319112,0.000259645,0.0001571471,0.0001942463,0.0001255324,0.0001432178,0.0002556096,0.0002051088,0.001655307],"category_scores_gemma":[0.0001593576,0.0001475575,0.0000637669,0.0001616484,0.0001359069,0.0002499517,0.0001471284,0.0002880671,0.0004145075],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001464388,"about_ca_system_score_gemma":0.0002662282,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007554676,"about_ca_topic_score_gemma":0.002043932,"domain_scores_codex":[0.9998949,0.00002125024,0.000003652342,0.00001558656,0.00002519107,0.00003945429],"domain_scores_gemma":[0.999936,0.000008970152,0.00001699871,0.000005107978,0.0000121133,0.00002075959],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002718849,0.00002615498,0.00009685085,0.00007815453,0.000003251548,0.0001613131,0.00005830533,0.0002074774,0.9952505,0.0005082839,0.0001565372,0.003181302],"study_design_scores_gemma":[0.00004270298,0.0003406027,0.000906976,0.000007795504,0.000005683039,0.0002713465,0.00003967504,0.0004513611,0.9937563,0.00007475591,0.004092081,0.0000107285],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9806055,0.002806292,0.004957585,0.00009992196,0.00006043017,0.00007878723,0.0002266859,0.00008317766,0.01108169],"genre_scores_gemma":[0.9913921,0.0009423744,0.003145428,0.00005126633,0.00001277897,0.00003445813,0.000284708,0.00002302139,0.004113881],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001655307,"threshold_uncertainty_score":0.00553757,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01232371747633314,"score_gpt":0.2326564845107,"score_spread":0.2203327670343668,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}