{"id":"W2077212464","doi":"10.1039/b708756j","title":"Spin-canting in heavy atom heterocyclic radicals","year":2007,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":101,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brockhouse Institute for Materials Research; McMaster University; University of Waterloo","funders":"","keywords":"Radical; Spin canting; Atom (system on chip); Spin (aerodynamics); Chemistry; Atomic physics; Computational chemistry; Physics; Organic chemistry; Thermodynamics; Magnetic field; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001023486,0.0001459211,0.0001515279,0.0002332775,0.0002908059,0.0003439534,0.0001876746,0.0001923977,0.001427074],"category_scores_gemma":[0.0001454895,0.0000688019,0.00007722361,0.00008639602,0.0003871115,0.0002115057,0.0002765038,0.0002020926,0.0001609557],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002139204,"about_ca_system_score_gemma":0.0001536321,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003916081,"about_ca_topic_score_gemma":0.0008273902,"domain_scores_codex":[0.9999481,0.000008070961,0.000003727412,0.00001007711,0.0000139139,0.00001601179],"domain_scores_gemma":[0.9998997,0.00001820209,0.00002633484,0.00001286405,0.00001956785,0.00002326873],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002530751,0.00001548007,0.0004370282,0.00005875848,0.000006516565,0.0001324158,0.00008259709,0.0001738665,0.9955705,0.001396225,0.000105633,0.001768005],"study_design_scores_gemma":[0.0001100657,0.0005411516,0.002884757,0.000007754581,0.00001746519,0.0003249039,0.00008463066,0.001752474,0.9911876,0.0006341197,0.002440537,0.00001452149],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990594,0.00009454077,0.0001369428,0.00002740178,0.000007133471,0.000002129973,0.00001520109,0.00001710154,0.0006402878],"genre_scores_gemma":[0.9991929,0.00004687143,0.0001151594,0.000006354984,0.000002905182,0.000002112809,0.00002640617,0.000005195936,0.0006021769],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001427074,"threshold_uncertainty_score":0.004774094,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0454968755297748,"score_gpt":0.3416735847572956,"score_spread":0.2961767092275208,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}