{"id":"W2077462394","doi":"10.1016/j.jchromb.2005.06.033","title":"Validated HPLC assay for iron determination in biological matrices based on ferrioxamine formation","year":2005,"lang":"en","type":"article","venue":"Journal of Chromatography B","topic":"Drug Transport and Resistance Mechanisms","field":"Medicine","cited_by":20,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Chromatography; Detection limit; Reproducibility; Calibration curve; Chelation; High-performance liquid chromatography; Acetonitrile; Selectivity; Catalysis; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001637314,0.001152713,0.0006146099,0.001139774,0.0005984491,0.0005352683,0.0008384714,0.001226709,0.0009820365],"category_scores_gemma":[0.001703098,0.0005116964,0.0004284194,0.0003283967,0.0006527836,0.0003680401,0.0004215128,0.001165859,0.00102734],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008189561,"about_ca_system_score_gemma":0.001313598,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001525794,"about_ca_topic_score_gemma":0.003872618,"domain_scores_codex":[0.9987277,0.0004082157,0.00008518033,0.0002272607,0.0004475124,0.0001041015],"domain_scores_gemma":[0.99884,0.0003759157,0.0001430232,0.0001179562,0.000431281,0.00009188958],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001604689,0.0001223822,0.0003416115,0.0000615198,0.00002602129,0.00005073824,0.0000472033,0.0001478662,0.992773,0.0001914885,0.0001756565,0.005902027],"study_design_scores_gemma":[0.00003141035,0.0004804015,0.001275931,0.00001757148,0.00003499824,0.0002889655,0.00001841235,0.0015304,0.993753,0.00009804523,0.002453977,0.00001688805],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.4600651,0.008089129,0.5182894,0.0006535195,0.000508216,0.001510224,0.001549795,0.002778151,0.006556461],"genre_scores_gemma":[0.6653218,0.003116756,0.3142156,0.0008616983,0.0001401658,0.0012596,0.002589381,0.0002014351,0.01229351],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.001637314,"threshold_uncertainty_score":0.008659005,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01963382466051449,"score_gpt":0.2781224256991636,"score_spread":0.2584886010386491,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}