{"id":"W2077466405","doi":"10.1039/c1cc12646f","title":"Mono-acylation of a polyamine-β-cyclodextrin based on guest mediated acyl migration","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Acylation; Cyclodextrin; Chemistry; Yield (engineering); Thioester; Polyamine; Fluorescence; Combinatorial chemistry; Organic chemistry; Biochemistry; Materials science; Enzyme; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000101645,0.0001114282,0.0001434892,0.00004481195,0.00004881178,0.000006078801,0.0004809165,0.0001361654,0.00003953626],"category_scores_gemma":[0.0003344027,0.0001048718,0.0001294663,0.0001797795,0.000139505,0.000003958897,0.0001245441,0.00009477337,0.0000112257],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001525542,"about_ca_system_score_gemma":0.00002700627,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008344806,"about_ca_topic_score_gemma":0.00003520017,"domain_scores_codex":[0.9992588,0.00005421697,0.0002794751,0.0001873806,0.0001062624,0.0001139308],"domain_scores_gemma":[0.9985052,0.00008391584,0.0001301402,0.001115508,0.00009648889,0.00006879192],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000424496,0.0002937418,0.002057766,0.000005764461,0.00002380076,6.102897e-8,0.00003009502,0.000002637516,0.9965224,0.00008550283,0.0002801371,0.0006556041],"study_design_scores_gemma":[0.0002186179,0.00004213949,0.001421326,0.00001706584,0.00003541404,3.327953e-7,0.00002040362,0.002987359,0.9909794,0.00006159867,0.004097105,0.00011926],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898301,0.0002852512,0.001026169,0.0006784589,0.00001894991,0.0001234947,0.00004500505,0.00002432702,0.007968234],"genre_scores_gemma":[0.9955307,0.0001344471,0.003151938,0.0001094373,0.00004419505,0.00003337276,0.0009373917,0.00001343731,0.00004509785],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007923136,"threshold_uncertainty_score":0.427655,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0350428818966582,"score_gpt":0.2576652075855841,"score_spread":0.2226223256889259,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}