{"id":"W2077466405","doi":"10.1039/c1cc12646f","title":"Mono-acylation of a polyamine-β-cyclodextrin based on guest mediated acyl migration","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Acylation; Cyclodextrin; Chemistry; Yield (engineering); Thioester; Polyamine; Fluorescence; Combinatorial chemistry; Organic chemistry; Biochemistry; Materials science; Enzyme; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002009764,0.0002996178,0.0001491267,0.0001107418,0.00009052928,0.0002294509,0.0001118562,0.0002066846,0.0008100322],"category_scores_gemma":[0.0002855258,0.0001277148,0.0001503569,0.0001325434,0.0001728891,0.0002439535,0.0001796735,0.0003482671,0.0003185749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001715351,"about_ca_system_score_gemma":0.0001463785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003468377,"about_ca_topic_score_gemma":0.0005309479,"domain_scores_codex":[0.9998708,0.00002654274,0.00001097976,0.00003835226,0.00002781656,0.00002559997],"domain_scores_gemma":[0.9997649,0.00007151322,0.00006122528,0.00003270731,0.00002995426,0.00003971642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004794527,0.000007207222,0.00006218191,0.000007692085,0.000001456497,0.00001304516,0.00001096485,0.00003395872,0.9992722,0.00004721505,0.000006594239,0.0004897629],"study_design_scores_gemma":[7.908352e-7,0.00003212232,0.0002117859,5.480855e-7,0.000001312206,0.00001438578,0.000001969272,0.0001799165,0.9994007,0.000003013074,0.0001523631,0.000001068165],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961441,0.000139136,0.002884675,0.00001715266,0.00001041694,0.00001371416,0.00005032373,0.00003322546,0.0007072825],"genre_scores_gemma":[0.9958971,0.0001468642,0.002089433,0.00001114438,0.000002522892,0.00001322195,0.00010254,0.00001737515,0.001719885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008100322,"threshold_uncertainty_score":0.002709806,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0350428818966582,"score_gpt":0.2576652075855841,"score_spread":0.2226223256889259,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}