{"id":"W2077503484","doi":"10.1002/chin.201515028","title":"ChemInform Abstract: Highly Diastereoselective Generation of Various 3,3‐Disubstituted Allyl Boronates for the Stereospecific Construction of Quaternary Centers.","year":2015,"lang":"en","type":"article","venue":"ChemInform","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Stereospecificity; Organic chemistry; Stereochemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001985748,0.000511874,0.0001158209,0.0004361142,0.0002318227,0.0002375517,0.000247206,0.0002263852,0.005971042],"category_scores_gemma":[0.0001043682,0.0001418369,0.000124166,0.0002323558,0.0001871209,0.0002376552,0.000274281,0.0003694045,0.001750994],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004541864,"about_ca_system_score_gemma":0.0005194685,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000964305,"about_ca_topic_score_gemma":0.003491279,"domain_scores_codex":[0.9999088,0.0000131341,0.000004187984,0.0000148396,0.00002256121,0.00003654538],"domain_scores_gemma":[0.9999548,0.000005308822,0.000009767529,0.000005253743,0.000009377936,0.00001544874],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003004844,0.00005065685,0.0002125286,0.0001566747,0.00001454409,0.0001409099,0.00006795575,0.000501843,0.979124,0.003657119,0.001618342,0.0141549],"study_design_scores_gemma":[0.00002961428,0.0001422821,0.0004796548,0.000008445947,0.000009414257,0.0001130357,0.00001288122,0.0003320923,0.9877861,0.0001774178,0.01089934,0.000009784304],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8398554,0.00298175,0.03898021,0.0005480724,0.0002848677,0.0002913201,0.005352568,0.001369608,0.1103363],"genre_scores_gemma":[0.9799427,0.001279783,0.008014314,0.0000835381,0.00001446865,0.00003484223,0.001454223,0.00008487298,0.009091228],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005971042,"threshold_uncertainty_score":0.01997513,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03067161081103628,"score_gpt":0.2437998637874513,"score_spread":0.213128252976415,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}