{"id":"W2077528173","doi":"10.1021/jo900335z","title":"Phenol-Based Lipophilic Fluorescent Antioxidant Indicators: A Rational Approach","year":2009,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; BODIPY; Photochemistry; Intramolecular force; Antioxidant; Fluorescence; Adduct; Fluorophore; Phenol; Redox; Solvent; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004524552,0.0002239856,0.0003100804,0.00004018103,0.0001507181,0.00004866978,0.0007323053,0.0001533535,0.002484352],"category_scores_gemma":[0.0001506866,0.000150974,0.0001883903,0.0002769858,0.0001413892,0.00008414203,0.00003398631,0.000634985,0.00001109897],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001203013,"about_ca_system_score_gemma":0.0003483678,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":9.680369e-7,"about_ca_topic_score_gemma":1.370507e-7,"domain_scores_codex":[0.9982443,0.00002267658,0.0006182551,0.0001601617,0.0006568161,0.0002978266],"domain_scores_gemma":[0.9986634,0.00007720323,0.000569289,0.0003896765,0.0001043215,0.0001961523],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009373998,0.0004829872,0.0002463223,0.0000853762,0.0000576325,0.0000217845,0.00008363287,0.00003568208,0.9957286,0.000011477,0.001483958,0.001668781],"study_design_scores_gemma":[0.001334775,0.00003996021,0.001418282,0.0001624401,0.0001071154,0.0006189843,0.0001315636,0.0003826644,0.9943474,0.000284956,0.0009498653,0.0002220192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922668,0.001302211,0.0009086911,0.001658103,0.00005184549,0.00003894656,0.00001027533,0.00005189494,0.003711255],"genre_scores_gemma":[0.9979241,0.0001280045,0.0005500058,0.0002390842,0.0008997852,6.132192e-7,0.000007649748,0.00002341797,0.0002272658],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005657397,"threshold_uncertainty_score":0.9984275,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007810742806428054,"score_gpt":0.2113021586099257,"score_spread":0.2034914158034977,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}