{"id":"W2077586575","doi":"10.1021/om501018r","title":"Reactivity of the Chiral Metallic Brønsted Acid [(η<sup>6</sup>-<i>p</i>-MeC<sub>6</sub>H<sub>4</sub><i>i</i>Pr)Ru(κ<sup>3</sup><i>P</i>,<i>O,O</i>′-<b>POH</b>)][SbF<sub>6</sub>]<sub>2</sub>(<b>POH</b>= (<i>S</i><sub>C1</sub>,<i>R</i><sub>C2</sub>)-Ph<sub>2</sub>PC(Ph)HC(OH)HCH<sub>2</sub>OMe) toward Aldimines","year":2014,"lang":"fa","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Consejo Superior de Investigaciones Científicas; Ministerio de Economía y Competitividad; European Social Fund; Ryerson University","keywords":"Aldimine; Chemistry; Deprotonation; Aniline; Reactivity (psychology); Medicinal chemistry; Catalysis; Cyclopentadiene; Diimine; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001390566,0.0003080754,0.000165979,0.0001430506,0.00009759723,0.000246436,0.0003184653,0.0002852031,0.001589875],"category_scores_gemma":[0.0002512062,0.0001106686,0.00008276965,0.0001137514,0.0001706264,0.0001362673,0.0001196757,0.0002526486,0.0004215144],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003092713,"about_ca_system_score_gemma":0.0001715486,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001532612,"about_ca_topic_score_gemma":0.001916679,"domain_scores_codex":[0.9998595,0.00002106813,0.000006183418,0.00002916051,0.00004314085,0.00004092811],"domain_scores_gemma":[0.9999322,0.0000159077,0.00001769837,0.000008059217,0.00001182567,0.00001441366],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002341264,0.00001820431,0.000225561,0.00006567237,0.00001031038,0.00005103538,0.00002681472,0.0002780209,0.9973224,0.0001872618,0.00010497,0.001475677],"study_design_scores_gemma":[0.000007506844,0.0001523898,0.00069055,0.000003374223,0.00000477653,0.00005006403,0.000009918715,0.0006949794,0.9976421,0.00001550401,0.0007254792,0.000003333846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945427,0.000847877,0.0006222608,0.00004583326,0.00002380453,0.000008144929,0.0001480963,0.00005970098,0.003701551],"genre_scores_gemma":[0.9977602,0.000328997,0.000369806,0.00001546451,0.000004922917,0.000002889899,0.0001615899,0.000008658637,0.001347528],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001589875,"threshold_uncertainty_score":0.005318642,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01181011002825303,"score_gpt":0.2101613386671515,"score_spread":0.1983512286388985,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}