{"id":"W2078029958","doi":"10.1039/b606938j","title":"Ionic liquids enable electrospray ionisation mass spectrometry in hexane","year":2006,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Hexane; Electrospray; Mass spectrometry; Toluene; Chemistry; Ionic liquid; Electrospray ionization; Ionic bonding; Chromatography; Analyte; Electrospray mass spectrometry; Extractive electrospray ionization; Analytical Chemistry (journal); Hydrocarbon; Polar; Sample preparation in mass spectrometry; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001903921,0.0002089491,0.0002447981,0.000169254,0.000198027,0.00007321531,0.001176369,0.0002212393,0.001615537],"category_scores_gemma":[0.00006456617,0.000233465,0.0001118496,0.0009916204,0.0001730072,0.000124093,0.0002233617,0.0006812246,0.00006239714],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005207515,"about_ca_system_score_gemma":0.00006663237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002654755,"about_ca_topic_score_gemma":0.00005402063,"domain_scores_codex":[0.9984378,0.00002973628,0.0005208347,0.0003551102,0.0002153711,0.0004411035],"domain_scores_gemma":[0.9974295,0.0002083877,0.0001429426,0.002068575,0.00007181969,0.00007872051],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006019638,0.0003021114,0.001739482,0.00001878417,0.000006712538,6.058237e-7,0.000009857933,0.000006168501,0.8623121,0.1345325,0.0009034034,0.0001622194],"study_design_scores_gemma":[0.0003342602,0.00001499008,0.0003193913,0.00003102889,0.00001752282,0.00001015968,0.00003113802,0.001028491,0.8865409,0.08837498,0.02300398,0.0002931401],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2943586,0.001758174,0.003935,0.006955835,0.00002121348,0.0003406742,0.00004681212,0.0008979069,0.6916859],"genre_scores_gemma":[0.9621568,0.0003050624,0.03471619,0.0000697037,0.0001115803,0.0003390723,0.0005808539,0.00003616215,0.0016846],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6900012,"threshold_uncertainty_score":0.9992971,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01307239359108858,"score_gpt":0.2606967187725913,"score_spread":0.2476243251815027,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}