{"id":"W2078070648","doi":"10.1021/jp810358k","title":"Atmospheric Chemistry of 4:2 Fluorotelomer Acrylate [C<sub>4</sub>F<sub>9</sub>CH<sub>2</sub>CH<sub>2</sub>OC(O)CH═CH<sub>2</sub>]: Kinetics, Mechanisms, and Products of Chlorine-Atom- and OH-Radical-Initiated Oxidation","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Radical; Reaction rate constant; Yield (engineering); Diluent; Torr; Kinetics; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000137376,0.0005281256,0.0001615498,0.0002577114,0.0004349413,0.0002696496,0.0002648396,0.0006408121,0.003265591],"category_scores_gemma":[0.0001498043,0.0001211266,0.0001533725,0.0001280945,0.0001879818,0.0004017827,0.0002083047,0.0003331419,0.0003957922],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007486331,"about_ca_system_score_gemma":0.0002191897,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01020342,"about_ca_topic_score_gemma":0.004971948,"domain_scores_codex":[0.9998831,0.000009023249,0.000002164993,0.00003812183,0.00004224897,0.00002544113],"domain_scores_gemma":[0.9999609,0.00000675855,0.000007589426,0.00000277392,0.00001562307,0.000006304697],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002644171,0.00002416086,0.006275263,0.0001217697,0.00001792253,0.00008229675,0.00006225185,0.0005322315,0.9851004,0.0002128411,0.000551766,0.00675455],"study_design_scores_gemma":[0.00005442361,0.0004707333,0.09770761,0.00001266693,0.00003770291,0.0002245461,0.00009782479,0.003195588,0.8872749,0.0002552264,0.01063988,0.00002896313],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917955,0.001634248,0.00149007,0.00008867178,0.00004498328,0.00002668131,0.0009719696,0.0001613408,0.003786612],"genre_scores_gemma":[0.9951461,0.0005124158,0.0007389674,0.00002845947,0.00001770138,0.00001144911,0.000636181,0.00002454506,0.002884173],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01020342,"threshold_uncertainty_score":0.02028805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01082479789843892,"score_gpt":0.231690621933483,"score_spread":0.2208658240350441,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}