{"id":"W2078155471","doi":"10.1021/ol049740t","title":"Anionic O → α- and β-Vinyl Carbamoyl Translocation of 2-(<i>O</i>-Carbamoyl) Stilbenes","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Sonogashira coupling; Metalation; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Polymer chemistry; Organic chemistry; Palladium; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001025826,0.0001616484,0.0002509284,0.00008503796,0.00006036872,0.00002082442,0.0001768537,0.00009028039,0.0002373416],"category_scores_gemma":[0.00005047457,0.0001547714,0.0000857132,0.000336461,0.00009168468,0.00009916977,0.00002793976,0.0001000022,0.00001291774],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008738406,"about_ca_system_score_gemma":0.00004956111,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001578269,"about_ca_topic_score_gemma":0.00003282056,"domain_scores_codex":[0.9989916,0.0000106398,0.0002757219,0.0002861943,0.0002327218,0.0002031275],"domain_scores_gemma":[0.9993789,0.00006159521,0.0001187696,0.0003381427,0.00003132738,0.00007124915],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00000981141,0.00004683104,0.001162991,0.00006876593,0.00007774774,0.000003610826,0.0004353451,0.00001685212,0.9826328,0.0001262767,0.00008336856,0.0153356],"study_design_scores_gemma":[0.0006348619,0.00001438432,0.001225628,0.00005122925,0.0001111278,0.00001452059,0.0003303133,0.00001238352,0.9970348,0.00007409831,0.0003057002,0.0001909867],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951012,0.001132701,0.000955768,0.001930269,0.00004548952,0.00004255927,0.00001144855,0.00005266192,0.0007278714],"genre_scores_gemma":[0.9990419,0.0002340934,0.0002349646,0.0003013944,0.00009572911,0.000006577957,0.00001713975,0.00003124839,0.00003701946],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01514462,"threshold_uncertainty_score":0.6311395,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005721239937174632,"score_gpt":0.1859614556722724,"score_spread":0.1802402157350978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}