{"id":"W2078195898","doi":"10.1021/om060576i","title":"Rhodium(III) Peroxo Complexes Containing Carbene and Phosphine Ligands","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Carbene; IMes; Rhodium; Medicinal chemistry; Phosphine; Oxidative addition; Chelation; Proton NMR; Benzene; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001990863,0.0004498633,0.000338602,0.0001342047,0.0001481697,0.000492764,0.000711706,0.0004620571,0.001111929],"category_scores_gemma":[0.0003663017,0.0003174425,0.000164315,0.0001465159,0.0002754437,0.000353089,0.0004500446,0.0006324807,0.0006351201],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004355438,"about_ca_system_score_gemma":0.0001869868,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005736795,"about_ca_topic_score_gemma":0.0008926602,"domain_scores_codex":[0.9997835,0.00003372455,0.00002004955,0.0000442206,0.00005895488,0.00005953309],"domain_scores_gemma":[0.9998679,0.00002311298,0.00003397041,0.00002746117,0.00001928907,0.00002818148],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001814683,0.00002699648,0.0001346427,0.0001496893,0.00001071779,0.00009694086,0.00004009851,0.0002249156,0.9964775,0.0006919629,0.0002441429,0.00172093],"study_design_scores_gemma":[0.00004444482,0.0002129485,0.0004057813,0.000006873773,0.00001996518,0.000167939,0.00001579192,0.000976344,0.9938933,0.00006553719,0.004181169,0.000009916656],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826226,0.0009692921,0.008697131,0.0001250241,0.00005125858,0.0001171915,0.0003093022,0.0004558621,0.006652257],"genre_scores_gemma":[0.9870357,0.0005845073,0.007864677,0.00006572716,0.00001750697,0.00007674485,0.000353344,0.00009292807,0.003908944],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001111929,"threshold_uncertainty_score":0.003719747,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01074178196660779,"score_gpt":0.2339094346685663,"score_spread":0.2231676527019585,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}