{"id":"W2078297237","doi":"10.1007/s00706-012-0876-4","title":"Thermodynamic analysis of solubility data 1: phase diagrams of systems salt hydrate + water","year":2012,"lang":"de","type":"article","venue":"Monatshefte für Chemie - Chemical Monthly","topic":"Chemical and Physical Properties in Aqueous Solutions","field":"Chemical Engineering","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"National Institute of Standards and Technology","keywords":"Solubility; Liquidus; Thermodynamics; Isobaric process; Eutectic system; Phase diagram; Hydrate; Mole fraction; Chemistry; Phase (matter); Consistency (knowledge bases); Activity coefficient; Salt (chemistry); Phase equilibrium; Ionic bonding; Aqueous solution; Physical chemistry; Organic chemistry; Ion; Mathematics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000253619,0.0003314846,0.0005345367,0.001431862,0.0003317138,0.0002559811,0.0004481923,0.0002045399,0.005254882],"category_scores_gemma":[0.0009993775,0.0001644256,0.000431512,0.001096827,0.0002512026,0.0005088018,0.0002490185,0.0005076741,0.0007512241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004082352,"about_ca_system_score_gemma":0.0004391621,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003273276,"about_ca_topic_score_gemma":0.002533698,"domain_scores_codex":[0.9997993,0.00001932945,0.00001427193,0.00004049467,0.00009961188,0.00002689347],"domain_scores_gemma":[0.9995465,0.0001953634,0.00006356163,0.00002890021,0.0001455692,0.00002016155],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001895735,0.0002845948,0.0181142,0.0006844862,0.0001189291,0.0002118132,0.0003168106,0.02586396,0.9128343,0.005700387,0.002255232,0.03171955],"study_design_scores_gemma":[0.00003010233,0.000432524,0.02342401,0.00001486166,0.00004653647,0.0001600005,0.00007223433,0.06282946,0.907845,0.001245377,0.003860991,0.00003901878],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792646,0.000764038,0.01003063,0.00009734848,0.00001762599,0.00006536759,0.005368639,0.0004311189,0.00396053],"genre_scores_gemma":[0.9905756,0.0002712881,0.003264775,0.00001842336,0.000007767114,0.00006628638,0.004482432,0.00008125142,0.001232097],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005254882,"threshold_uncertainty_score":0.01757938,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03238761744735452,"score_gpt":0.2845155908592206,"score_spread":0.252127973411866,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}