{"id":"W2078386563","doi":"10.1021/es011311s","title":"Photochemical Mass Balance of 2,3,7,8-TeCDD in Aqueous Solution under UV Light Shows Formation of Chlorinated Dihydroxybiphenyls, Phenoxyphenols, and Dechlorination Products","year":2002,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Toxic Organic Pollutants Impact","field":"Environmental Science","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Fisheries and Oceans Canada; University of Guelph; University of Victoria","funders":"Division of Ocean Sciences; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Homolysis; Photochemistry; Aqueous solution; Biphenyl; Bond cleavage; Polychlorinated biphenyl; Environmental chemistry; Radical; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009507532,0.0003399259,0.0001584217,0.0001871441,0.0001407873,0.0001548445,0.0001925531,0.0003738439,0.001732555],"category_scores_gemma":[0.00008455756,0.0001048565,0.0001454721,0.0002422012,0.0001388604,0.0001940554,0.0001222158,0.0003341247,0.0003572474],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003058556,"about_ca_system_score_gemma":0.0001324065,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001197053,"about_ca_topic_score_gemma":0.001205268,"domain_scores_codex":[0.9998797,0.00001216608,0.00000551543,0.00003959493,0.00003838722,0.0000246392],"domain_scores_gemma":[0.9999423,0.00001440774,0.00001500339,0.000004086272,0.00001708609,0.000007100595],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002005869,0.000004661479,0.0001104232,0.00001428896,0.000002296681,0.00001739787,0.00001111978,0.00003881198,0.9991657,0.0000193311,0.00001409443,0.0005818848],"study_design_scores_gemma":[0.000001532669,0.00004954882,0.000672967,0.000001287744,0.000002500803,0.00002424088,0.00001014266,0.0003853831,0.9985951,0.00001194669,0.0002437674,0.000001565054],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908339,0.001414435,0.004570332,0.00007711213,0.00001868171,0.00001532247,0.0004050507,0.00009039506,0.002574695],"genre_scores_gemma":[0.9944764,0.0007511656,0.002149735,0.00003942394,0.000004814027,0.0000200352,0.0004090575,0.0000172813,0.002132075],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001732555,"threshold_uncertainty_score":0.005795956,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007879278359545069,"score_gpt":0.1981135549290444,"score_spread":0.1902342765694993,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}