{"id":"W2078422719","doi":"10.1002/ejic.200400290","title":"Synthesis, X‐ray Characterisation and Studies of the New Ionic Complex [Bis(pyridin‐2‐yl) disulfide] Triiodide, Obtained by Oxidation of 2‐Mercaptopyridine with I<sub>2</sub> − Implications in the Mechanism of Action of Antithyroid Drugs","year":2004,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Triiodide; Monoclinic crystal system; Dichloromethane; Ionic compound; Raman spectroscopy; Crystal structure; Crystallography; Medicinal chemistry; Ligand (biochemistry); Ionic bonding; Infrared spectroscopy; Stereochemistry; Inorganic chemistry; Ion; Organic chemistry; Physical chemistry; Solvent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001689297,0.0002073219,0.0001572592,0.0001193739,0.0001357017,0.0002656246,0.0002891918,0.0002369001,0.0005508011],"category_scores_gemma":[0.0002197385,0.0001227058,0.0001057106,0.0001699108,0.0001906847,0.0001354763,0.0001233459,0.0002095937,0.0002228636],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002384855,"about_ca_system_score_gemma":0.0001877908,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004909936,"about_ca_topic_score_gemma":0.000430664,"domain_scores_codex":[0.999934,0.00000816687,0.000006262496,0.00001472965,0.000027421,0.000009380514],"domain_scores_gemma":[0.9999219,0.000008484424,0.00002320222,0.000007214701,0.00002270701,0.0000165259],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005427165,0.000008738375,0.0001075956,0.00004704275,0.000004383463,0.00003386556,0.00002863873,0.0001101089,0.9985381,0.00007188126,0.00005558623,0.0009397615],"study_design_scores_gemma":[0.00001869363,0.000206157,0.001586061,0.000003916593,0.00001345685,0.0002436199,0.00002340004,0.000572276,0.9942624,0.00002605809,0.003037201,0.00000662491],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942363,0.0009764328,0.002955892,0.00006484349,0.00001848489,0.00002602557,0.0002493721,0.00005389323,0.001418721],"genre_scores_gemma":[0.9936739,0.000501782,0.003365582,0.00002662267,0.000006842728,0.00001772397,0.000457636,0.000027835,0.001922104],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005508011,"threshold_uncertainty_score":0.001842618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03520162736282059,"score_gpt":0.2504041850956425,"score_spread":0.2152025577328219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}