{"id":"W2078783754","doi":"10.1002/ejoc.200300023","title":"An Enantiodivergent Trend in Microbial Baeyer−Villiger Oxidations of Functionalized Pentalenones by Recombinant Whole Cells Expressing Monooxygenases from <i>Acinetobacter</i> and <i>Pseudomonas</i>","year":2003,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Enzyme Catalysis and Immobilization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Oesterreichische Nationalbank; Universität Wien; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Monooxygenase; Biotransformation; Cyclohexanone; Cyclopentanone; Pseudomonas; Stereochemistry; Recombinant DNA; Biocatalysis; Enzyme; Organic chemistry; Catalysis; Biochemistry; Bacteria; Cytochrome P450; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001879671,0.0003034631,0.0001596376,0.00008153255,0.00007250136,0.0003245317,0.0001109296,0.0001550048,0.000536971],"category_scores_gemma":[0.0001926548,0.0001311128,0.0001760923,0.00009572686,0.0001775018,0.0002126168,0.0001562758,0.0004343261,0.0001969943],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001115816,"about_ca_system_score_gemma":0.00009678258,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004711209,"about_ca_topic_score_gemma":0.0005669881,"domain_scores_codex":[0.9998615,0.00002740189,0.00001215858,0.00002728832,0.00004399119,0.00002765706],"domain_scores_gemma":[0.9998918,0.00003143767,0.00002668014,0.00001850711,0.00001658786,0.00001496629],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002468631,0.000007175183,0.0001672201,0.000008186662,0.000002447222,0.00002006581,0.00001508477,0.00003291814,0.9990914,0.00004299194,0.000003913294,0.0005838294],"study_design_scores_gemma":[0.000001500071,0.00005303925,0.0006644281,7.889126e-7,0.000004886481,0.00007607541,0.00001599542,0.00008562431,0.9989156,0.00001045572,0.0001701987,0.000001458964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965487,0.0003037495,0.002400712,0.00003956363,0.000006439968,0.000007390674,0.00006425254,0.00001618832,0.0006131336],"genre_scores_gemma":[0.9967271,0.0002732716,0.001963535,0.00001452382,0.000001532009,0.000005148539,0.0001222827,0.00001027628,0.0008822278],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000536971,"threshold_uncertainty_score":0.001796365,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006446807378348938,"score_gpt":0.1978273928441981,"score_spread":0.1913805854658492,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}