{"id":"W2078783754","doi":"10.1002/ejoc.200300023","title":"An Enantiodivergent Trend in Microbial Baeyer−Villiger Oxidations of Functionalized Pentalenones by Recombinant Whole Cells Expressing Monooxygenases from <i>Acinetobacter</i> and <i>Pseudomonas</i>","year":2003,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Enzyme Catalysis and Immobilization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Oesterreichische Nationalbank; Universität Wien; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Monooxygenase; Biotransformation; Cyclohexanone; Cyclopentanone; Pseudomonas; Stereochemistry; Recombinant DNA; Biocatalysis; Enzyme; Organic chemistry; Catalysis; Biochemistry; Bacteria; Cytochrome P450; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002592147,0.0001461385,0.0002046276,0.00002836201,0.00004839831,0.00003065253,0.0001397279,0.00004863852,0.0003203157],"category_scores_gemma":[0.0000476036,0.0001354756,0.00007898262,0.00008814,0.00005701746,0.00002317835,0.00003658163,0.00009336327,0.000001885926],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001592478,"about_ca_system_score_gemma":0.00004555789,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002633202,"about_ca_topic_score_gemma":0.000004052487,"domain_scores_codex":[0.9988832,0.0001564118,0.0005105158,0.0002238755,0.0001046459,0.000121352],"domain_scores_gemma":[0.9992383,0.00001273817,0.0003775214,0.0002010016,0.00008013257,0.00009030073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005258233,0.0002435722,0.001124553,0.00001526713,0.00004066625,0.000007004843,0.00007222025,0.00002306004,0.994588,1.93036e-7,0.003642696,0.0001901912],"study_design_scores_gemma":[0.00126338,0.00009277757,0.0007044093,0.00005425043,0.00004135838,0.00004641377,0.0002288407,0.000001985284,0.9728938,0.000002453547,0.02453123,0.0001391477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971845,0.001722541,0.0006216769,0.0000225886,0.0001132227,0.00003826696,0.00008505063,0.000002460079,0.0002097414],"genre_scores_gemma":[0.9978595,0.0007090771,0.0005342672,0.00004384114,0.00008326413,4.772563e-7,0.0004361617,0.00002520047,0.0003081863],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02169424,"threshold_uncertainty_score":0.5524535,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006446807378348938,"score_gpt":0.1978273928441981,"score_spread":0.1913805854658492,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}