{"id":"W2079029260","doi":"10.1021/ic900703e","title":"Experimental and Theoretical Investigations of the Contact Ion Pairs Formed by Reactions of the Anions [(EPR<sub>2</sub>)<sub>2</sub>N]<sup>−</sup> (R = <sup>i</sup>Pr, <sup>t</sup>Bu; E = S, Se) with the Cations [(TePR<sub>2</sub>)<sub>2</sub>N]<sup>+</sup> (R = <sup>i</sup>Pr, <sup>t</sup>Bu)","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Chalcogen; Denticity; Crystallography; Iodide; Tellurium; Bond length; Electron paramagnetic resonance; Ion; Cationic polymerization; Molecule; Molecular geometry; Crystal structure; Stereochemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000186662,0.000298111,0.0002570376,0.0001510909,0.0003747356,0.0002637568,0.0008410921,0.0005063504,0.006602032],"category_scores_gemma":[0.0004853251,0.0001746036,0.0001539813,0.000310705,0.00055976,0.0004954115,0.0002876752,0.0004231096,0.0006096732],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005440509,"about_ca_system_score_gemma":0.0002086564,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000615858,"about_ca_topic_score_gemma":0.0006405049,"domain_scores_codex":[0.9998571,0.00001717891,0.000003987826,0.00002865004,0.00006970001,0.00002340776],"domain_scores_gemma":[0.9998251,0.00007235337,0.00003529008,0.00002460489,0.00003529815,0.000007419499],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005806974,0.00008743961,0.001436481,0.0005390511,0.00001850635,0.0002888865,0.0002118988,0.004086229,0.9748755,0.009826563,0.0003934385,0.007655325],"study_design_scores_gemma":[0.00003564963,0.0002775746,0.002332475,0.000007189007,0.00001187799,0.0002497153,0.0001516093,0.01152556,0.981054,0.001112612,0.003227987,0.00001368268],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.978207,0.001046749,0.006461999,0.0001178973,0.00001953835,0.00003967955,0.0004239143,0.00008745172,0.01359573],"genre_scores_gemma":[0.9952851,0.0004145202,0.002626158,0.00001717047,0.000006049021,0.0000337955,0.0002229087,0.00001580188,0.001378605],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006602032,"threshold_uncertainty_score":0.02208596,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006265471635810474,"score_gpt":0.2121001562649843,"score_spread":0.2058346846291738,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}