{"id":"W2079127993","doi":"10.1021/om800740z","title":"Indenyl Hemilability: Unveiling a Masked (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ru(κ<sup>2</sup>-<i>P</i>,<i>C</i>arbene) Zwitterion Via Facile and Reversible Ru−C(sp<sup>3</sup>) Bond Cleavage","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Reactivity (psychology); Zwitterion; Adduct; Ligand (biochemistry); Medicinal chemistry; Lewis acids and bases; Stereochemistry; Metathesis; Crystallography; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.001539955,0.002696678,0.003378501,0.001090627,0.001849005,0.0007123205,0.002180853,0.001611698,0.005228769],"category_scores_gemma":[0.0008373869,0.00291962,0.001511143,0.003419869,0.001392341,0.001599614,0.001919235,0.002158521,0.001269414],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001112192,"about_ca_system_score_gemma":0.0006517428,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001355616,"about_ca_topic_score_gemma":0.00004235534,"domain_scores_codex":[0.986904,0.0003777111,0.003087002,0.004096085,0.002454476,0.003080672],"domain_scores_gemma":[0.9915989,0.0008787856,0.001097684,0.004177975,0.0005646206,0.001682019],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003581536,0.001436201,0.007388406,0.001275937,0.00150627,0.0003501911,0.005142021,0.001308724,0.9613364,0.00008294894,0.002906598,0.01690816],"study_design_scores_gemma":[0.003890636,0.0002869186,0.001363972,0.0003465508,0.001494381,0.0008663452,0.003674719,0.0115222,0.9281556,0.0006261141,0.04347675,0.00429581],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887412,0.002193694,0.0006421167,0.0006881941,0.0001491913,0.00101474,0.0008612783,0.0009711273,0.004738472],"genre_scores_gemma":[0.9896559,0.003065938,0.00118238,0.0007941803,0.001006736,0.0002171568,0.001212119,0.0006916117,0.00217398],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04057015,"threshold_uncertainty_score":0.9996844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01398875385282884,"score_gpt":0.1982556743154326,"score_spread":0.1842669204626038,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}