{"id":"W2079127993","doi":"10.1021/om800740z","title":"Indenyl Hemilability: Unveiling a Masked (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ru(κ<sup>2</sup>-<i>P</i>,<i>C</i>arbene) Zwitterion Via Facile and Reversible Ru−C(sp<sup>3</sup>) Bond Cleavage","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Reactivity (psychology); Zwitterion; Adduct; Ligand (biochemistry); Medicinal chemistry; Lewis acids and bases; Stereochemistry; Metathesis; Crystallography; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001735165,0.0004105524,0.0001671479,0.00009672576,0.00009442128,0.0003216937,0.0003810488,0.0003331358,0.00154016],"category_scores_gemma":[0.000235363,0.0001676507,0.0001434566,0.00009468249,0.0002614454,0.0003839601,0.00035062,0.0005203602,0.0004275548],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001776511,"about_ca_system_score_gemma":0.0001171799,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000191903,"about_ca_topic_score_gemma":0.0002944896,"domain_scores_codex":[0.9998969,0.00001737973,0.000005945379,0.00002333803,0.00002332917,0.00003304985],"domain_scores_gemma":[0.9998666,0.00002363265,0.00004230153,0.00003214441,0.00001304735,0.00002231731],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005940922,0.0000122357,0.00006862092,0.00002719421,0.000003916464,0.00008632812,0.00003253032,0.0001023976,0.9980697,0.0002339471,0.00002759233,0.001276239],"study_design_scores_gemma":[0.000004811046,0.000128831,0.0002688133,0.000001299559,0.000002941304,0.00008113246,0.000007524676,0.000333198,0.9983558,0.0000287177,0.0007835865,0.000003375619],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929883,0.0002580951,0.003677213,0.0000519777,0.00001119156,0.00002640825,0.00007950611,0.00009550319,0.002811867],"genre_scores_gemma":[0.9971306,0.000132518,0.00128163,0.00002297723,0.000002902264,0.00001163719,0.00007938573,0.00002182764,0.001316603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00154016,"threshold_uncertainty_score":0.005152345,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01398875385282884,"score_gpt":0.1982556743154326,"score_spread":0.1842669204626038,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}