{"id":"W2079155173","doi":"10.1063/1.3599607","title":"Electronic structure and optical properties of 2,5,8,11-tetra-tert-butylperylene polyhedral crystals from x-ray absorption near-edge structure and x-ray excited optical luminescence studies","year":2011,"lang":"en","type":"article","venue":"Applied Physics Letters","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"National Natural Science Foundation of China","keywords":"XANES; Luminescence; Excited state; Dodecahedron; X-ray spectroscopy; Materials science; Absorption (acoustics); X-ray; Crystallography; Spectroscopy; Analytical Chemistry (journal); Chemistry; Atomic physics; Optics; Optoelectronics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00007366904,0.0004721264,0.0006893137,0.00003527775,0.0001746967,0.00009753041,0.0002803809,0.0001750579,0.0001003727],"category_scores_gemma":[0.00003435959,0.000366946,0.00008240037,0.0001092214,0.0008596245,0.0001914411,0.0001999559,0.0003409058,0.000001868324],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007353998,"about_ca_system_score_gemma":0.00004160936,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009495108,"about_ca_topic_score_gemma":0.000008929534,"domain_scores_codex":[0.9980057,0.00002639653,0.0004767695,0.0006049543,0.0003598488,0.0005263006],"domain_scores_gemma":[0.9989849,0.0001460221,0.0001862227,0.000490516,0.00006651189,0.0001258075],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001882939,0.00006661523,0.003036799,0.0003228285,0.0002907243,0.000003255941,0.003465767,0.00002869077,0.9890522,0.0008146543,0.0000573538,0.002672779],"study_design_scores_gemma":[0.0009593242,0.00006695242,0.01698466,0.0002565352,0.0002731418,0.00001012161,0.00103488,0.0004313808,0.9775879,0.001631428,0.0000743925,0.0006892611],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982753,0.0008793723,0.0001057908,0.0002544912,0.00006221683,0.0002015034,0.00004591137,0.0000678482,0.0001074969],"genre_scores_gemma":[0.9972194,0.00006547198,0.002071615,0.0002831264,0.0002424652,0.00002452488,0.00002616389,0.00005626615,0.00001092874],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01394786,"threshold_uncertainty_score":0.9998782,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01971155720288998,"score_gpt":0.2055123156449328,"score_spread":0.1858007584420428,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}