{"id":"W2079195039","doi":"10.1021/ic801641u","title":"New Derivatives of PCP-Type Pincer Complexes of Nickel","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Pincer movement; Nickel; Type (biology); Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005864998,0.0002260785,0.0005065476,0.00002623425,0.000036564,0.0000126773,0.0005251679,0.0001340362,0.06296974],"category_scores_gemma":[0.0001436316,0.0002256997,0.0001766936,0.0003600422,0.0001077292,0.0000633213,0.00009929916,0.0001410551,0.00001850958],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004856216,"about_ca_system_score_gemma":0.0001712403,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005001012,"about_ca_topic_score_gemma":0.0000022292,"domain_scores_codex":[0.998629,0.000006530909,0.0005321666,0.0003119508,0.0002916725,0.0002286771],"domain_scores_gemma":[0.998673,0.00008304951,0.000327134,0.0006834661,0.0001155869,0.0001177338],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002661527,0.0001379488,0.0004987269,0.0001763145,0.000105968,0.00000131088,0.0001848093,0.000001194946,0.9895908,0.0001081896,0.0005191701,0.008648903],"study_design_scores_gemma":[0.0003191535,0.00001645738,0.003009956,0.00006959647,0.00006339476,0.000009393045,0.0002445264,0.00001041338,0.9914906,0.0005692857,0.003981997,0.0002152156],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9677727,0.001044199,0.00007325417,0.000140413,0.00002025511,0.00002580421,0.00002942152,0.00005298695,0.03084101],"genre_scores_gemma":[0.9925638,0.0000639342,0.0005189051,0.00002532303,0.0001525847,6.918355e-7,0.00004015012,0.00002198047,0.006612623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06295123,"threshold_uncertainty_score":0.9378868,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01389243126731198,"score_gpt":0.234294171294319,"score_spread":0.220401740027007,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}