{"id":"W2079296217","doi":"10.1021/om0492045","title":"Synthesis of Acyclic NPNCN Systems and Metalation Reactions with Organolithium, -magnesium, and -aluminum Reagents","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Metalation; Denticity; Reagent; Nucleophile; Medicinal chemistry; Ligand (biochemistry); Magnesium; Nuclear magnetic resonance spectroscopy; Stereochemistry; Organic chemistry; Catalysis; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001874979,0.0002829573,0.0001896816,0.0002844249,0.0002385342,0.0002736418,0.0005451776,0.0001736743,0.002672632],"category_scores_gemma":[0.0002410024,0.0001763541,0.0001506362,0.0002844488,0.0001806941,0.0002830024,0.0004744643,0.0003525638,0.0007183313],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009390469,"about_ca_system_score_gemma":0.0003777782,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001930143,"about_ca_topic_score_gemma":0.005211209,"domain_scores_codex":[0.999824,0.00001961461,0.00001759725,0.00004801207,0.00004796228,0.00004291741],"domain_scores_gemma":[0.999921,0.000008785622,0.00001761827,0.00001630788,0.0000147974,0.00002147338],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002020398,0.00004832428,0.0003143626,0.0004829073,0.0000178641,0.000283884,0.0001926449,0.000855356,0.969247,0.006563473,0.001084918,0.02070711],"study_design_scores_gemma":[0.00002855495,0.0003533285,0.0009817217,0.00002007629,0.00003395664,0.0003613913,0.00004074261,0.001129586,0.9515298,0.0003239938,0.04517226,0.00002450337],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9097827,0.004841535,0.02460842,0.0002359083,0.0001815705,0.0003672288,0.002473167,0.0009753791,0.05653411],"genre_scores_gemma":[0.9573479,0.002416029,0.024839,0.0001353095,0.0000232628,0.0002206002,0.002043073,0.00008518661,0.01288962],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002672632,"threshold_uncertainty_score":0.008940876,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01133885210654385,"score_gpt":0.2086356725620238,"score_spread":0.19729682045548,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}