{"id":"W2079406908","doi":"10.1021/ic051773x","title":"Hydroxy- and Mercaptopyridine Pincer Platinum and Palladium Complexes Generated by Silver-Free Halide Abstraction","year":2006,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Nederlandse Organisatie voor Wetenschappelijk Onderzoek; Russian Foundation for Basic Research","keywords":"Chemistry; Pincer movement; Palladium; Platinum; Halide; Abstraction; Polymer chemistry; Photochemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007419653,0.0004175864,0.0003364312,0.00001450241,0.0002189229,0.0001519781,0.0003055971,0.0003287414,0.002176763],"category_scores_gemma":[0.00005974047,0.0004617402,0.00006627811,0.000120113,0.0002270218,0.0001222925,0.0002124595,0.000380245,0.000009110187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009350345,"about_ca_system_score_gemma":0.00005060072,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003840267,"about_ca_topic_score_gemma":0.00002118322,"domain_scores_codex":[0.9981844,0.000008990745,0.0004305819,0.0006668697,0.0002871451,0.0004220084],"domain_scores_gemma":[0.998904,0.00007575783,0.0001857907,0.0005933588,0.00006184774,0.000179177],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003181454,0.00008469114,0.002973431,0.0002461105,0.00005776113,0.00002689818,0.00002288888,0.00001025573,0.9880443,0.00001464822,0.008336878,0.0001503509],"study_design_scores_gemma":[0.001216958,0.000007170369,0.0004230478,0.00004551623,0.00006396067,0.0003053045,0.0001280657,0.0003462089,0.9888867,0.0005672604,0.007497924,0.000511885],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9806738,0.001928269,0.00002545623,0.0002962111,0.00003425492,0.00004850015,0.0002533976,0.0002130488,0.01652704],"genre_scores_gemma":[0.9950944,0.00007898513,0.0001810362,0.00006603822,0.0004154272,0.00001574546,0.0007433941,0.00005820737,0.003346767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01442057,"threshold_uncertainty_score":0.9997835,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005706666077837807,"score_gpt":0.194351897481502,"score_spread":0.1886452314036642,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}