{"id":"W2079418194","doi":"10.1021/om300017u","title":"Frustrated Lewis Pair Behavior of Intermolecular Amine/B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> Pairs","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":147,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Lewis acids and bases; Adduct; Frustrated Lewis pair; Medicinal chemistry; Amine gas treating; Base (topology); Iminium; Borane; Salt (chemistry); Hydride; Boranes; Stereochemistry; Catalysis; Boron; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001424703,0.000251239,0.0002435896,0.0001374789,0.0003932894,0.0004001309,0.000301382,0.000286657,0.003051752],"category_scores_gemma":[0.0002878565,0.0002191702,0.0001440795,0.000102137,0.0002579272,0.0003587479,0.0004672999,0.0002667283,0.0004682047],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001925408,"about_ca_system_score_gemma":0.000119644,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003899836,"about_ca_topic_score_gemma":0.0007550371,"domain_scores_codex":[0.9998139,0.00002764461,0.000006066764,0.00002862914,0.00005820127,0.00006562719],"domain_scores_gemma":[0.9998531,0.00002939167,0.00003916885,0.00001645949,0.000018984,0.00004281653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002143727,0.0000457831,0.0006946226,0.00009124379,0.0000454243,0.0003043416,0.0001696231,0.001399876,0.991931,0.002118654,0.0002101995,0.002774914],"study_design_scores_gemma":[0.00003022588,0.0003713486,0.00168064,0.000005975351,0.00002103175,0.0003250577,0.0001075249,0.01023287,0.9849929,0.0004895236,0.001722044,0.00002098259],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966739,0.0001619447,0.0009724756,0.00001494752,0.000009152479,0.000009897247,0.00001716597,0.00003465936,0.002105807],"genre_scores_gemma":[0.9987225,0.00005649151,0.0003165523,0.00001121636,0.000002327948,0.000005757234,0.00003147733,0.00001132218,0.0008422992],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003051752,"threshold_uncertainty_score":0.01020914,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0129462871090329,"score_gpt":0.2198183646640704,"score_spread":0.2068720775550375,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}