{"id":"W2079599679","doi":"10.1021/ic200046k","title":"Characterization of Noninnocent Metal Complexes Using Solid-State NMR Spectroscopy: <i>o</i>-Dioxolene Vanadium Complexes","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"National Center for Research Resources","keywords":"Chemistry; Chemical shift; Vanadium; Solid-state nuclear magnetic resonance; Nuclear magnetic resonance spectroscopy; Spectroscopy; Anisotropy; Chemical physics; Analytical Chemistry (journal); Crystallography; Computational chemistry; Physical chemistry; Nuclear magnetic resonance; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005485069,0.0002877129,0.0003882965,0.00002756316,0.0001255628,0.00001770562,0.0004035152,0.0001292485,0.002621361],"category_scores_gemma":[0.00001394553,0.0003174742,0.0001107111,0.0002215024,0.0001744697,0.0001243998,0.0001471039,0.0002331542,0.00001025412],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001381801,"about_ca_system_score_gemma":0.00008910531,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001015116,"about_ca_topic_score_gemma":0.000005985172,"domain_scores_codex":[0.9984645,0.000006811286,0.0005439518,0.0004096255,0.0002029005,0.0003721907],"domain_scores_gemma":[0.9987096,0.00001699893,0.0004102638,0.0006009976,0.0001349937,0.0001271189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002036909,0.0001767537,0.0005033331,0.0001886481,0.00004766695,0.000004033867,0.0001642475,0.000009826385,0.998663,0.00008776239,0.00002222999,0.0001121023],"study_design_scores_gemma":[0.0002554813,0.00001009294,0.0002305327,0.00006745783,0.00005604148,0.00004214274,0.00006940633,0.0004308488,0.9966698,0.0007044331,0.001152141,0.0003115756],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9861233,0.00005225064,0.008926633,0.00002508548,0.00001366924,0.0001032694,0.0003238341,0.0002293339,0.004202571],"genre_scores_gemma":[0.9925564,0.0000621697,0.006468459,0.00004802533,0.0001245223,0.00001303729,0.0002801042,0.00006457726,0.0003827318],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00643302,"threshold_uncertainty_score":0.9999278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02547414606621801,"score_gpt":0.2700218101998663,"score_spread":0.2445476641336483,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}