{"id":"W2079702983","doi":"10.1139/v99-249","title":"The one- and two-photon photochemistry of benzylsilacyclobutanes, acyclic benzylsilanes, and 1,1,2-triphenylsilacyclobutane","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; McMaster University","keywords":"Chemistry; Photodissociation; Photochemistry; Radical; Flash photolysis; Methylene; Methanol; Yield (engineering); Derivative (finance); Toluene; Absorption spectroscopy; Medicinal chemistry; Organic chemistry; Reaction rate constant; Kinetics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001033591,0.0003418377,0.0001499629,0.0001740877,0.00014836,0.0001558436,0.0001729633,0.0002685504,0.001425116],"category_scores_gemma":[0.0001385202,0.0001322244,0.0001671469,0.0001405613,0.0001824871,0.000198177,0.0001196924,0.0004060461,0.0002445852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000232814,"about_ca_system_score_gemma":0.0001606663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004637882,"about_ca_topic_score_gemma":0.001022141,"domain_scores_codex":[0.9999243,0.000008620126,0.000002938142,0.00001624376,0.00002577552,0.00002212731],"domain_scores_gemma":[0.9999007,0.00003807872,0.00002761013,0.000006840231,0.0000132417,0.0000134767],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000324825,0.000005305415,0.0001085777,0.00004444729,0.000002409271,0.00003225032,0.00002171752,0.00005633569,0.9988824,0.00004278753,0.000006793674,0.000764596],"study_design_scores_gemma":[0.000004298289,0.0001110481,0.001154527,0.000002736785,0.000003867167,0.00004974824,0.00001864671,0.0001623128,0.9981902,0.00001895677,0.0002814175,0.000002276534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962667,0.001347953,0.0008140674,0.00002884898,0.00000947381,0.000009689997,0.00007151407,0.00001702829,0.001434684],"genre_scores_gemma":[0.9964129,0.0009643133,0.0009335679,0.0000177116,0.000004129358,0.00001022146,0.00009337232,0.000007301395,0.001556364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001425116,"threshold_uncertainty_score":0.004767478,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007729296727252122,"score_gpt":0.1944722761143887,"score_spread":0.1867429793871366,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}