{"id":"W2079870613","doi":"10.1139/cjc-2011-0493","title":"Direct and facile synthesis of acyl azides from carboxylic acids using the trichloroisocyanuric acid–triphenylphosphine system","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Trichloroisocyanuric acid; Triphenylphosphine; Carboxylic acid; Organic chemistry; Acylation; Combinatorial chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004573467,0.0009556467,0.0005403241,0.0003802565,0.0004116846,0.0003955516,0.0005825154,0.0004937273,0.001504487],"category_scores_gemma":[0.0002561556,0.0003325149,0.0003981943,0.0003846557,0.0002792578,0.0004473208,0.000596208,0.001242604,0.001240469],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004290552,"about_ca_system_score_gemma":0.0005745706,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007804954,"about_ca_topic_score_gemma":0.001320922,"domain_scores_codex":[0.9996769,0.00004324353,0.00003053666,0.00006074858,0.0001138276,0.00007474655],"domain_scores_gemma":[0.9998275,0.00003105259,0.00004151215,0.00002744812,0.00003649014,0.00003597577],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003349883,0.00001357236,0.0000398533,0.00007465299,0.000006002688,0.0001140763,0.00001988385,0.0001166526,0.995804,0.0003354538,0.0001123567,0.003329887],"study_design_scores_gemma":[0.00001065657,0.0001005373,0.0001513939,0.000003547897,0.000007763202,0.0002322732,0.000003997496,0.0002689895,0.9947226,0.00004801716,0.004441584,0.000008703964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.562469,0.01246293,0.3979987,0.000870529,0.0004365592,0.0008349661,0.002007868,0.002708742,0.02021058],"genre_scores_gemma":[0.842853,0.01102931,0.1334178,0.0001802266,0.0001007763,0.0003977852,0.001610975,0.0003552521,0.01005479],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001504487,"threshold_uncertainty_score":0.005033016,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005760103839205311,"score_gpt":0.1811057481021293,"score_spread":0.175345644262924,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}