{"id":"W2080015429","doi":"10.1139/v02-047","title":"Catalytic reduction of benzoate esters and lactones in the presence of PhMeSiH<sub>2</sub> and a titanocene-based catalyst","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Catalysis; Toluene; Medicinal chemistry; Cyclopentadienyl complex; Alkoxy group; Yield (engineering); Stoichiometry; Stereochemistry; Organic chemistry; Alkyl","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001931869,0.0001221968,0.0002827857,0.00008686836,0.0000408078,0.00003138334,0.0002348312,0.00007373958,0.0002911913],"category_scores_gemma":[0.0001344939,0.0001029421,0.00007855109,0.000189568,0.0002557841,0.00009113877,0.00001117898,0.0001578094,3.484024e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005584426,"about_ca_system_score_gemma":0.0001781205,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005333997,"about_ca_topic_score_gemma":0.0004823531,"domain_scores_codex":[0.9991103,0.00001419301,0.0004039439,0.0001332885,0.0001713263,0.0001668882],"domain_scores_gemma":[0.9990602,0.00009141209,0.0003338495,0.0002427047,0.0000798429,0.0001920141],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001234966,0.00003332974,0.002237719,0.0004058312,0.0000566389,0.00003942065,0.0008375492,0.0000171406,0.9903874,0.000002735916,0.0000957833,0.005874109],"study_design_scores_gemma":[0.0003159851,0.00001102338,0.00112281,0.000190106,0.000091013,0.0003166625,0.001006764,0.00009068903,0.9965132,0.00002650796,0.0002092947,0.0001059414],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960736,0.002284807,0.000002390539,0.0003538328,0.00001520347,0.00002313836,0.00003774932,0.000001441826,0.001207817],"genre_scores_gemma":[0.9997599,0.00008812812,0.00001829183,0.00000875682,0.00004818043,0.000001439905,0.000005920348,0.00001027961,0.00005916542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006125809,"threshold_uncertainty_score":0.4197857,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01277227881762216,"score_gpt":0.186253932853732,"score_spread":0.1734816540361098,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}