{"id":"W2080022417","doi":"10.1021/jp077420w","title":"Temperature Dependence of the Rate Coefficients for the Reactions of Br Atoms with Dimethyl Ether and Diethyl Ether","year":2008,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"","keywords":"Diethyl ether; Dimethyl ether; Ether; Chemistry; Medicinal chemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001694022,0.00126319,0.000637378,0.001056548,0.0002504221,0.0005934629,0.00147421,0.0006375147,0.006628583],"category_scores_gemma":[0.006551596,0.001101153,0.001164865,0.0004987424,0.0005326893,0.001651538,0.0004746495,0.002514131,0.003682833],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001336933,"about_ca_system_score_gemma":0.0006401425,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002450345,"about_ca_topic_score_gemma":0.001936115,"domain_scores_codex":[0.9988092,0.0001169074,0.00007502818,0.0003894117,0.0004195209,0.0001899766],"domain_scores_gemma":[0.9957419,0.00200811,0.0004968662,0.0003354759,0.001295835,0.0001217506],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006849018,0.0001614212,0.007106943,0.0009042951,0.0001579229,0.0002230233,0.0004276195,0.01218559,0.9539531,0.004612712,0.001275427,0.01830695],"study_design_scores_gemma":[0.00003324254,0.0001766779,0.009459309,0.00004314724,0.00007256802,0.0002562874,0.00008733213,0.01978702,0.9638609,0.0006174562,0.005504918,0.000101114],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.786759,0.01270198,0.1602947,0.0009808657,0.0007707152,0.0008131213,0.006386299,0.002332574,0.02896081],"genre_scores_gemma":[0.9444566,0.0075819,0.02562599,0.0001880471,0.00005356824,0.0007290795,0.004074245,0.0007261187,0.01656443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006628583,"threshold_uncertainty_score":0.02217478,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01041213465158364,"score_gpt":0.2191731163109995,"score_spread":0.2087609816594159,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}