{"id":"W2080047812","doi":"10.1021/ic300892p","title":"Homoleptic Pnictogen–Chalcogen Coordination Complexes","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Teknologiateollisuuden 100-Vuotisjuhlasäätiö; Jyväskylän Yliopisto; Academy of Finland","keywords":"Pnictogen; Chalcogen; Chemistry; Homoleptic; Selenide; Tellurium; Trifluoromethanesulfonate; Reagent; Arsenic; Selenium; Ligand (biochemistry); Medicinal chemistry; Stereochemistry; Crystallography; Organic chemistry; Metal; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006091444,0.0001829572,0.0001705025,0.0001797716,0.0002076796,0.0002872816,0.0002295929,0.0001643596,0.001235517],"category_scores_gemma":[0.0001723675,0.0001014432,0.00004079354,0.0002174391,0.0001659087,0.0001214817,0.0002434384,0.0001592529,0.0002272056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003890596,"about_ca_system_score_gemma":0.0001863023,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006304,"about_ca_topic_score_gemma":0.001501706,"domain_scores_codex":[0.9998707,0.00001569047,0.000008969283,0.00003021037,0.00004550753,0.00002894208],"domain_scores_gemma":[0.9999349,0.000007706434,0.00001381159,0.00001042201,0.00001812506,0.00001498334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001197948,0.00001136746,0.0002828936,0.00007196557,0.000009925117,0.00009239232,0.0000283724,0.000179184,0.9963334,0.0004212121,0.0002048273,0.002244626],"study_design_scores_gemma":[0.00002281468,0.0001220423,0.001325928,0.00000266759,0.000009860491,0.0002564809,0.00002364806,0.0004671771,0.9949964,0.00006725871,0.002700538,0.000005176172],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949326,0.0002642451,0.001041621,0.0000266911,0.000005955236,0.00001955666,0.0002163793,0.00003151693,0.003461402],"genre_scores_gemma":[0.9963955,0.000180105,0.001284994,0.00001416703,0.000003576872,0.00001426037,0.000338161,0.00001156954,0.001757659],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001235517,"threshold_uncertainty_score":0.004133224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01741851752229768,"score_gpt":0.2279902104268828,"score_spread":0.2105716929045851,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}