{"id":"W2080049571","doi":"10.1039/b814486a","title":"Reactions of phosphines with electron deficient boranes","year":2009,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":97,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; University of Windsor","funders":"Natural Sciences and Engineering Research Council of Canada; NOVA Chemicals","keywords":"Boranes; Chemistry; Electron; Photochemistry; Organic chemistry; Boron; Physics; Nuclear physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00003279126,0.0001693072,0.0001872163,0.00004595006,0.0001345643,0.00001690125,0.000131853,0.0001061711,0.002070994],"category_scores_gemma":[0.000006099464,0.0001513229,0.00008478651,0.0002682977,0.00006810911,0.00009946422,0.000001243919,0.0002286441,0.00001274852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005301365,"about_ca_system_score_gemma":0.00008018009,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005505992,"about_ca_topic_score_gemma":0.00005208276,"domain_scores_codex":[0.9990672,0.000004737909,0.0002509344,0.0002408636,0.0001971165,0.0002391222],"domain_scores_gemma":[0.999373,0.00003069022,0.00008966395,0.000334995,0.00007544144,0.00009617954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006800909,0.000394551,0.0002321471,0.00008206684,0.00003279903,0.000003044117,0.0001434541,0.0001909245,0.9970928,0.0001460371,0.0001658864,0.001448324],"study_design_scores_gemma":[0.0004436766,0.00006684434,0.0006476372,0.00003754724,0.00006975899,0.00004684549,0.0001724004,0.00003667505,0.9922603,0.00003799073,0.006009384,0.0001709049],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.979412,0.0003164162,0.003147172,0.00123431,0.00008291668,0.00007339572,0.00008535719,0.0002950162,0.01535347],"genre_scores_gemma":[0.9980521,0.0001324134,0.0002703616,0.00006531968,0.00006009362,0.000007884496,0.00002943478,0.00001946966,0.00136296],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01864012,"threshold_uncertainty_score":0.9988412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006178236270007184,"score_gpt":0.2219855020125162,"score_spread":0.215807265742509,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}