{"id":"W2080069329","doi":"10.1063/1.2716390","title":"Symmetry segregation of the vibronic levels within the S1←S system of thiophosgene, Cl2CS, by optical-optical double resonance spectroscopy","year":2007,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Basic Energy Sciences; National Research Council Canada; U.S. Department of Energy","keywords":"Chemistry; Singlet state; Spectroscopy; Resonance (particle physics); Dipole; Atomic physics; Excitation; Symmetry (geometry); Antisymmetric relation; Vibronic spectroscopy; Laser; Molecular electronic transition; Fluorescence; Molecular physics; Excited state; Physics; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000677597,0.0002272566,0.0004372771,0.00001376136,0.00009778449,0.00002047137,0.001019566,0.0001903817,0.00002518194],"category_scores_gemma":[0.00008795037,0.000112171,0.0002993857,0.0003061163,0.0004704704,0.00007975339,0.0001215278,0.001089646,0.000002066442],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001658956,"about_ca_system_score_gemma":0.0001510836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008673664,"about_ca_topic_score_gemma":8.522283e-7,"domain_scores_codex":[0.9977344,0.0000502945,0.0008588312,0.0001472989,0.0008949988,0.000314131],"domain_scores_gemma":[0.9977582,0.0003281036,0.0009863881,0.0006481203,0.0001896456,0.00008958664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005450616,0.00007050637,0.00005947979,0.0001775058,0.00009126071,0.000002040343,0.0002293339,0.00006958896,0.9536563,0.04464666,0.0003058342,0.0001464507],"study_design_scores_gemma":[0.0007110314,0.00004831715,0.000069486,0.0002610173,0.0001733168,0.00007716742,0.000212296,0.0001640826,0.9890894,0.009004981,0.00007383676,0.000115095],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898548,0.001279496,0.003128043,0.0004572184,0.0001675677,0.0001056094,0.00002076635,0.00001077511,0.004975685],"genre_scores_gemma":[0.9982943,0.00002682267,0.001176361,0.00006633205,0.0003501251,8.354026e-7,0.000002209806,0.00002726595,0.00005574085],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03564168,"threshold_uncertainty_score":0.4734029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007470034678086943,"score_gpt":0.2401155675505848,"score_spread":0.2326455328724978,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}