{"id":"W2080112798","doi":"10.1016/j.tet.2012.12.026","title":"Aryl substituted adamantane–dipyrromethanes: chromogenic and fluorescent anion sensors","year":2012,"lang":"en","type":"article","venue":"Tetrahedron","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"University of Victoria","keywords":"Chemistry; Adamantane; Substituent; Chromogenic; Fluorescence; Molecule; Aryl; Derivative (finance); Proton NMR; Ion; Crystal structure; Fluorescence spectroscopy; Nitro; Binding constant; Photochemistry; Stereochemistry; Crystallography; Organic chemistry; Alkyl; Binding site","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004679189,0.0004454988,0.0002665757,0.0002504892,0.0001321575,0.000376425,0.0005006753,0.0004321117,0.001076375],"category_scores_gemma":[0.0002143432,0.0002516821,0.0001503445,0.0002553614,0.000287716,0.0004073845,0.0002814101,0.0007483816,0.0006914196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003088512,"about_ca_system_score_gemma":0.0001216041,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002399679,"about_ca_topic_score_gemma":0.0005845446,"domain_scores_codex":[0.9997258,0.0000684277,0.00001810462,0.00005624583,0.00008347493,0.00004805793],"domain_scores_gemma":[0.9998939,0.00002175876,0.00003441927,0.00001375277,0.00001636222,0.00001984891],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000122585,0.00001503301,0.00006115153,0.00004373155,0.000003480435,0.0000813086,0.00002645243,0.00007551033,0.9950575,0.0005560688,0.0001352993,0.003822009],"study_design_scores_gemma":[0.00001033127,0.000127134,0.0002190374,0.000002983112,0.000008003813,0.0001673425,0.0000102055,0.0004856,0.9962462,0.00005153248,0.002666478,0.000005188702],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8991275,0.0138391,0.07072721,0.0006445632,0.0002184893,0.00008212727,0.0003376836,0.0008418558,0.01418145],"genre_scores_gemma":[0.9557779,0.007111362,0.0246713,0.0002194178,0.00008737666,0.00005650022,0.0002814974,0.00006517502,0.0117294],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001076375,"threshold_uncertainty_score":0.003600836,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01074363534637323,"score_gpt":0.2189053341244006,"score_spread":0.2081616987780274,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}