{"id":"W2080579590","doi":"10.1039/c4nr05888g","title":"Photoluminescent silicon nanocrystals with chlorosilane surfaces – synthesis and reactivity","year":2014,"lang":"en","type":"article","venue":"Nanoscale","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chlorosilane; Hydrosilylation; Silane; Surface modification; Silicon; Materials science; Silanes; Reagent; Reactivity (psychology); Hydride; Polymer chemistry; Nucleophile; Nanocrystal; Salt (chemistry); Chemical engineering; Organic chemistry; Chemistry; Nanotechnology; Catalysis; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001698183,0.0002940625,0.0001925806,0.000115846,0.0001303943,0.0002437796,0.0003441425,0.0003762966,0.0007588891],"category_scores_gemma":[0.0001532805,0.0002125105,0.0002510254,0.00008316008,0.0002251987,0.0001904093,0.0002212345,0.0003272042,0.0003234466],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000295895,"about_ca_system_score_gemma":0.000198586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004658776,"about_ca_topic_score_gemma":0.001000056,"domain_scores_codex":[0.9998866,0.00001120425,0.000009727431,0.00002781649,0.00004240453,0.0000220761],"domain_scores_gemma":[0.9998888,0.00002753527,0.00002741339,0.0000231678,0.00001712641,0.00001597743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001208723,0.000004703926,0.00004062409,0.0000181646,0.000002013044,0.0000313763,0.000009726807,0.00003699212,0.9992047,0.0000779597,0.00001268924,0.0005490719],"study_design_scores_gemma":[0.000004576733,0.00005130933,0.0003591929,0.000001395604,0.000002961229,0.00007912868,0.000004342472,0.0002295198,0.9984906,0.00001532054,0.0007589981,0.000002672483],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9836835,0.001200126,0.01078129,0.0001035874,0.00002529022,0.00005110587,0.0001438464,0.00010762,0.003903601],"genre_scores_gemma":[0.9843076,0.0007203143,0.01217239,0.00005198613,0.00001357784,0.0000484199,0.0002396761,0.00003375635,0.002412225],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007588891,"threshold_uncertainty_score":0.002538741,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007474093720046289,"score_gpt":0.209018382992493,"score_spread":0.2015442892724467,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}